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The one-dimensional organic-inorganic hybrid: catena-poly[bis-[1-(3-ammonio-prop-yl)-1H-imidazolium] [[iodidoplumbate(II)]-tri-?-iodido-plumbate(II)-tri-?-iodido-[iodidoplumbate(II)]-di-?-iodido]].
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ABSTRACT:
SUBMITTER: Trigui A
PROVIDER: S-EPMC3099864 | biostudies-other | 2011 Apr
REPOSITORIES: biostudies-other
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The one-dimensional organic-inorganic hybrid: catena-poly[bis-[1-(3-ammonio-prop-yl)-1H-imidazolium] [[iodidoplumbate(II)]-tri-μ-iodido-plumbate(II)-tri-μ-iodido-[iodidoplumbate(II)]-di-μ-iodido]].
Acta crystallographica. Section E, Structure reports online 20110315 Pt 4
The organic-inorganic hybrid, {(C(6)H(13)N(3))(2)[Pb(3)I(10)]}(n), was obtained by the reaction of 1-(3-ammonio-prop-yl)imidazolium triiodide and PbI(2) at room temperature. The structure contains one-dimensional {[Pb(3)I(10)](4-)}(n) polymeric anions spreading parallel to [001], resulting from face-face-edge association of PbI(6) distorted octa-hedra. One of the Pb(II) cations is imposed at an inversion centre, whereas the second occupies a general position. N-H⋯I hydrogen bonds connect the org ...[more]