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Bis(dimethyl-ammonium) tetra-chlorido-dimethyl-stannate(IV).

ABSTRACT: Regular crystals of the title compound, (C(2)H(8)N)(2)[Sn(CH(3))(2)Cl(4)], were obtained by reacting SnMe(2)Cl(2) with (CH(3))(2)NH·HCl in ethanol in a 1:1 ratio. The Sn atom lies on a center of symmetry and is six-coordinated. It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms in cis positions. The Cl atoms are connected to dimethyl-ammonium cations through N-H?Cl hydrogen bonds, forming an infinite chain extending parallel to [010].

SUBMITTER: Diop T

PROVIDER: S-EPMC3120357 | biostudies-other | 2011 Jun

REPOSITORIES: biostudies-other

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Bis(dimethyl-ammonium) tetra-chlorido-dimethyl-stannate(IV).

Diop Tidiane T Diop Libasse L Michaud Francois F

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

Regular crystals of the title compound, (C(2)H(8)N)(2)[Sn(CH(3))(2)Cl(4)], were obtained by reacting SnMe(2)Cl(2) with (CH(3))(2)NH·HCl in ethanol in a 1:1 ratio. The Sn atom lies on a center of symmetry and is six-coordinated. It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms in cis positions. The Cl atoms are connected to dimethyl-ammonium cations through N-H⋯Cl hydrogen bonds, forming an infinite chain extending parallel to [010]. ...[more]

PMID: 21754600

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