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Tribenzyl-chlorido(triphenyl-phosphine oxide-?O)tin(IV).

ABSTRACT: In the title tribenzyl-chloridotin-triphenyl-phosphine adduct, [Sn(C(7)H(7))(3)Cl(C(18)H(15)OP)], the Sn(IV) atom is in a trans-C(3)SnClO trigonal-bipyramidal geometry and is displaced out of the C(3)Sn girdle in the direction of the axial Cl atom by 0.112?(1) in one independent mol-ecule and by 0.167?(1)?Å in the other. The phenyl ring of one of the six benzyl units was refined as equally disordered over two sets of sites.

SUBMITTER: Lo KM

PROVIDER: S-EPMC3120498 | biostudies-other | 2011 Jun

REPOSITORIES: biostudies-other

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Tribenzyl-chlorido(triphenyl-phosphine oxide-κO)tin(IV).

Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110528 Pt 6

In the title tribenzyl-chloridotin-triphenyl-phosphine adduct, [Sn(C(7)H(7))(3)Cl(C(18)H(15)OP)], the Sn(IV) atom is in a trans-C(3)SnClO trigonal-bipyramidal geometry and is displaced out of the C(3)Sn girdle in the direction of the axial Cl atom by 0.112 (1) in one independent mol-ecule and by 0.167 (1) Å in the other. The phenyl ring of one of the six benzyl units was refined as equally disordered over two sets of sites. ...[more]

PMID: 21754684

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