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Catena-Poly[[[4,6-bis-(2-pyrid-yl)-1,3,5-triazin-2-olato]copper(II)]-?-chlorido].

ABSTRACT: The title compound, [Cu(C(13)H(8)N(5)O)Cl](n), has a chain structure parallel to [100] with Cu(2+) cations in a trigonal-bipyramidal coordination environment. The ligand adopts a tridentate tripyridyl coordination mode and a chloride ion acts as a bridge. The chains are linked via weak C-H?O and C-H?Cl hydrogen bonds into a three-dimensional supra-molecular network.

SUBMITTER: Cao ML

PROVIDER: S-EPMC3120550 | biostudies-other | 2011 Jun

REPOSITORIES: biostudies-other

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catena-Poly[[[4,6-bis-(2-pyrid-yl)-1,3,5-triazin-2-olato]copper(II)]-μ-chlorido].

Cao Man-Li ML

Acta crystallographica. Section E, Structure reports online 20110511 Pt 6

The title compound, [Cu(C(13)H(8)N(5)O)Cl](n), has a chain structure parallel to [100] with Cu(2+) cations in a trigonal-bipyramidal coordination environment. The ligand adopts a tridentate tripyridyl coordination mode and a chloride ion acts as a bridge. The chains are linked via weak C-H⋯O and C-H⋯Cl hydrogen bonds into a three-dimensional supra-molecular network. ...[more]

PMID: 21754632

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