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(E)-N'-(2-Chloro-5-nitro-benzyl-idene)-3-meth-oxy-benzohydrazide monohydrate.

ABSTRACT: In the hydrazone mol-ecule of the title compound, C(15)H(12)ClN(3)O(4)·H(2)O, the two benzene rings form a dihedral angle of 3.6?(1)°. In the crystal structure, the solvent water mol-ecules are involved in the formation of inter-molecular N-H?O and O-H?N hydrogen bonds, which link the mol-ecules into double ribbons extending along the b axis. Inter-molecular ?-? inter-actions between the aromatic rings [centroid-centroid distances = 3.712?(3) and 3.672?(3)?Å] link these ribbons further into layers parallel to the ab plane.

SUBMITTER: Liu SY 

PROVIDER: S-EPMC3151800 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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(E)-N'-(2-Chloro-5-nitro-benzyl-idene)-3-meth-oxy-benzohydrazide monohydrate.

Liu Shi-Yong SY   Wang Xiao-Ling XL  

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

In the hydrazone mol-ecule of the title compound, C(15)H(12)ClN(3)O(4)·H(2)O, the two benzene rings form a dihedral angle of 3.6 (1)°. In the crystal structure, the solvent water mol-ecules are involved in the formation of inter-molecular N-H⋯O and O-H⋯N hydrogen bonds, which link the mol-ecules into double ribbons extending along the b axis. Inter-molecular π-π inter-actions between the aromatic rings [centroid-centroid distances = 3.712 (3) and 3.672 (3) Å] link these ribbons further into laye  ...[more]

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