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Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop-yl]imino-meth-yl}phenolate)zinc.

ABSTRACT: In the zwitterionic zinc title complex, [ZnCl(2)(C(14)H(20)N(2)O(2))], the Zn(II) ion is four-coordinated in a distorted tetra-hedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetra-hedral coordination environment. In the crystal, a pair of N-H?O hydrogen bonds connect the mol-ecules into a centrosymmetric dimer. C-H?O, C-H?Cl and C-H?? inter-actions are also observed.

SUBMITTER: Ikmal Hisham NA

PROVIDER: S-EPMC3151802 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Dichlorido(2-{[3-(morpholin-4-ium-4-yl)prop-yl]imino-meth-yl}phenolate)zinc.

Ikmal Hisham Nurul Azimah NA Khaledi Hamid H Mohd Ali Hapipah H

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

In the zwitterionic zinc title complex, [ZnCl(2)(C(14)H(20)N(2)O(2))], the Zn(II) ion is four-coordinated in a distorted tetra-hedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetra-hedral coordination environment. In the crystal, a pair of N-H⋯O hydrogen bonds connect the mol-ecules into a centrosymmetric dimer. C-H⋯O, C-H⋯Cl and C-H⋯π inter-actions are also observed. ...[more]

PMID: 21836916

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