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Hexa-kis-(1-benzyl-1H-imidazole-?N)manganese(II) bis-(perchlorate).

ABSTRACT: In the title compound, [Mn(C(10)H(10)N(2))(6)](ClO(4))(2), the Mn(II) ion, located on an inversion center, is coordinated by six N atoms from three pairs of symmetry-related 1-benzyl-1H-imidazole ligands in a distorted octa-hedral geometry. In the crystal, weak inter-molecular C-H?O hydrogen bonds link the complex cations and perchlorate anions.

SUBMITTER: Dong GY

PROVIDER: S-EPMC3151807 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Hexa-kis-(1-benzyl-1H-imidazole-κN)manganese(II) bis-(perchlorate).

Dong Gui-Ying GY Liu Tong-Fei TF He Cui-Hong CH Deng Xiao-Chen XC Shi Xiao-Ge XG

Acta crystallographica. Section E, Structure reports online 20110622 Pt 7

In the title compound, [Mn(C(10)H(10)N(2))(6)](ClO(4))(2), the Mn(II) ion, located on an inversion center, is coordinated by six N atoms from three pairs of symmetry-related 1-benzyl-1H-imidazole ligands in a distorted octa-hedral geometry. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds link the complex cations and perchlorate anions. ...[more]

PMID: 21836938

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