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Bis(2-ethyl-1H-imidazole-?N)bis-(nitrito-?O,O')copper(II) dihydrate.

ABSTRACT: In the title compound, [Cu(NO(2))(2)(C(5)H(8)N(2))]·2H(2)O, the Cu(2+) ion exhibits site symmetry 2 and is hexacoordinated by four O atoms from two nitrite ions and two N atoms from two 2-ethyl-1H-imidazole mol-ecules. A free water mol-ecule assists in forming a three-dimensional network holding together the complexes via O-H?N, O-H?O and N-H?O hydrogen bonds.

SUBMITTER: Zhu RQ

PROVIDER: S-EPMC3151815 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Bis(2-ethyl-1H-imidazole-κN)bis-(nitrito-κO,O')copper(II) dihydrate.

Zhu Run-Qiang RQ

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

In the title compound, [Cu(NO(2))(2)(C(5)H(8)N(2))]·2H(2)O, the Cu(2+) ion exhibits site symmetry 2 and is hexacoordinated by four O atoms from two nitrite ions and two N atoms from two 2-ethyl-1H-imidazole mol-ecules. A free water mol-ecule assists in forming a three-dimensional network holding together the complexes via O-H⋯N, O-H⋯O and N-H⋯O hydrogen bonds. ...[more]

PMID: 21836921

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