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Bis(2-amino-6-methyl-1,3-benzothia-zole-?N)bis-(4-nitro-benzoato-?O)zinc.

ABSTRACT: In the title mononuclear complex, [Zn(C(7)H(4)NO(4))(2)(C(8)H(8)N(2)S)(2)], the Zn(II) atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia-zole and by two carboxylate O atoms from two 4-nitro-benzoate ligands, adopting a slightly distorted tetra-hedral coordination geometry. In the crystal, inter-molecular N-H?O hydrogen bonds between the amino group of 2-amino-6-methyl-1,3-benzothia-zole and the carboxyl-ate group of 4-nitro-benzoate link these discrete mononuclear units into a one-dimensional supra-molecular chain extending parallel to [100].

SUBMITTER: Sun XT

PROVIDER: S-EPMC3151824 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Bis(2-amino-6-methyl-1,3-benzothia-zole-κN)bis-(4-nitro-benzoato-κO)zinc.

Sun Xue-Tong XT Wang Xiu-Guang XG Zhao Xiao-Jun XJ

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

In the title mononuclear complex, [Zn(C(7)H(4)NO(4))(2)(C(8)H(8)N(2)S)(2)], the Zn(II) atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia-zole and by two carboxylate O atoms from two 4-nitro-benzoate ligands, adopting a slightly distorted tetra-hedral coordination geometry. In the crystal, inter-molecular N-H⋯O hydrogen bonds between the amino group of 2-amino-6-methyl-1,3-benzothia-zole and the carboxyl-ate group of 4-nitro-benzoate link these discrete mononuclear units ...[more]

PMID: 21836917

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