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Poly[bis[?-1,3-bis-(imidazol-1-ylmeth-yl)benzene-?N:N]bis-(nitrato-?O)cadmium].

ABSTRACT: A novel metal-organic framework based on 1,3-bis-(imidazol-1-ylmeth-yl)benzene (1,3-bimb), [Cd(NO(3))(2)(C(14)H(14)N(4))(2)](n), has been synthesized hydro-thermally. The structure exhibits a two-dimensional metal-organic (4,4)-net composed of Cd(II) atoms and bimb ligands, and such layers are further joined through inter-layer C-H?O hydrogen bonds to generate a three-dimensional supra-molecular structure.

SUBMITTER: Hu XY

PROVIDER: S-EPMC3151839 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Poly[bis[μ-1,3-bis-(imidazol-1-ylmeth-yl)benzene-κN:N]bis-(nitrato-κO)cadmium].

Hu Xi-Ying XY Yang Guang-Rui GR Shan Wen-Wen WW

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

A novel metal-organic framework based on 1,3-bis-(imidazol-1-ylmeth-yl)benzene (1,3-bimb), [Cd(NO(3))(2)(C(14)H(14)N(4))(2)](n), has been synthesized hydro-thermally. The structure exhibits a two-dimensional metal-organic (4,4)-net composed of Cd(II) atoms and bimb ligands, and such layers are further joined through inter-layer C-H⋯O hydrogen bonds to generate a three-dimensional supra-molecular structure. ...[more]

PMID: 21836888

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