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[1,2-Bis-(diisopropyl-phosphan-yl)ethane-?P,P']dichloridonickel(II).

ABSTRACT: In the crystal structure of title compound, [NiCl(2)(C(14)H(32)P(2))], the Ni(II) atom lies on a twofold rotation axis and shows a slightly distorted square-planar coordination geometry, with a dihedral angle of 10.01?(8)° between the cis-Cl-Ni-Cl and cis-P-Ni-P planes. There is no significant inter-molecular inter-action except very weak C-H?Cl inter-actions. The crystal studied was a racemic twin.

SUBMITTER: Castellanos-Blanco NY

PROVIDER: S-EPMC3151871 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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[1,2-Bis-(diisopropyl-phosphan-yl)ethane-κP,P']dichloridonickel(II).

Castellanos-Blanco Nahury Y NY García Juventino J JJ Flores-Alamo Marcos M

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

In the crystal structure of title compound, [NiCl(2)(C(14)H(32)P(2))], the Ni(II) atom lies on a twofold rotation axis and shows a slightly distorted square-planar coordination geometry, with a dihedral angle of 10.01 (8)° between the cis-Cl-Ni-Cl and cis-P-Ni-P planes. There is no significant inter-molecular inter-action except very weak C-H⋯Cl inter-actions. The crystal studied was a racemic twin. ...[more]

PMID: 21836867

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