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Poly[(?(5)-3,5-dinitro-benzoato)rubidium].

ABSTRACT: The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(6))](n), comprises an Rb cation and a 3,5-dinitro-benzoate anion. The Rb cation is eight-coordinated by O atoms from five 3,5-dinitro-benzoate anions. On the other hand, each 3,5-dinitro-benzoate anion links five Rb cations with the carboxyl-ate groups as ?(3)-bridging. The metal atom is firstly linked by the carboxyl-ate groups into a chain along the c-axis direction, which is further linked by bonds between the Rb and nitro O atoms, giving a three-dimensional framework.

SUBMITTER: Miao Y 

PROVIDER: S-EPMC3151889 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Poly[(μ(5)-3,5-dinitro-benzoato)rubidium].

Miao Yanqing Y   Zhang Xiaoqing X   Liu Chunye C  

Acta crystallographica. Section E, Structure reports online 20110630 Pt 7

The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(6))](n), comprises an Rb cation and a 3,5-dinitro-benzoate anion. The Rb cation is eight-coordinated by O atoms from five 3,5-dinitro-benzoate anions. On the other hand, each 3,5-dinitro-benzoate anion links five Rb cations with the carboxyl-ate groups as μ(3)-bridging. The metal atom is firstly linked by the carboxyl-ate groups into a chain along the c-axis direction, which is further linked by bonds between the Rb and nitro O atoms,  ...[more]

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