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Bis(?-2-{1-[2-(dimethyl-amino)-ethyl-imino]-eth-yl}phenolato)bis-[bromido-copper(II)] monohydrate.

ABSTRACT: In the centrosymmetric dinuclear copper(II) title complex, [Cu(2)Br(2)(C(12)H(17)N(2)O)(2)]·H(2)O, each Cu(II) ion is five coordinated in a square-pyramidal geometry by the N,N',O-tridentate Schiff base, one Br atom and the bridging O atom of the centrosymmetrically related Schiff base. In the crystal, the water mol-ecules link the complex mol-ecules into infinite chains along the b axis via O-H?Br and C-H?O hydrogen bonds.

SUBMITTER: Suleiman Gwaram N

PROVIDER: S-EPMC3151890 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Bis(μ-2-{1-[2-(dimethyl-amino)-ethyl-imino]-eth-yl}phenolato)bis-[bromido-copper(II)] monohydrate.

Suleiman Gwaram Nura N Khaledi Hamid H Mohd Ali Hapipah H

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

In the centrosymmetric dinuclear copper(II) title complex, [Cu(2)Br(2)(C(12)H(17)N(2)O)(2)]·H(2)O, each Cu(II) ion is five coordinated in a square-pyramidal geometry by the N,N',O-tridentate Schiff base, one Br atom and the bridging O atom of the centrosymmetrically related Schiff base. In the crystal, the water mol-ecules link the complex mol-ecules into infinite chains along the b axis via O-H⋯Br and C-H⋯O hydrogen bonds. ...[more]

PMID: 21836915

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