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Catena-Poly[bis-[(1,10-phenanthroline)cobalt(II)]-?(4)-3,6-dicarb-oxy-cyclo-hexane-1,2,4,5-tetra-carboxyl-ato].

ABSTRACT: In the title compound, [Co(2)(C(12)H(8)O(12))(C(12)H(8)N(2))(2)](n), each 3,6-dicarb-oxy-cyclo-hexane-1,2,4,5-tetra-carboxyl-ate (H(2)chhc(4-)) anion has crystallographically imposed C(2) symmetry and bridges four six-coordinate Co atoms, generating polymeric chains running along [010]. These chains are further extended into a three-dimensional network via O-H?O hydrogen-bonding inter-actions and inter-chain ?-? stacking inter-actions [centroid-centroid distance = 3.662?(2)?Å].

SUBMITTER: Xu W

PROVIDER: S-EPMC3151899 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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catena-Poly[bis-[(1,10-phenanthroline)cobalt(II)]-μ(4)-3,6-dicarb-oxy-cyclo-hexane-1,2,4,5-tetra-carboxyl-ato].

Xu Wei W

Acta crystallographica. Section E, Structure reports online 20110604 Pt 7

In the title compound, [Co(2)(C(12)H(8)O(12))(C(12)H(8)N(2))(2)](n), each 3,6-dicarb-oxy-cyclo-hexane-1,2,4,5-tetra-carboxyl-ate (H(2)chhc(4-)) anion has crystallographically imposed C(2) symmetry and bridges four six-coordinate Co atoms, generating polymeric chains running along [010]. These chains are further extended into a three-dimensional network via O-H⋯O hydrogen-bonding inter-actions and inter-chain π-π stacking inter-actions [centroid-centroid distance = 3.662 (2) Å]. ...[more]

PMID: 21836841

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