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Catena-[[(nitrato-?O)silver(I)]-?-1,10-phenanthroline-5,6-dione-?O,O':N,N'].

ABSTRACT: In the title one-dimensional coordination polymer, [Ag(NO(3))(C(12)H(6)N(2)O(2))](n), the Ag(I) atom is penta-coordinated by two N atoms from a 1,10-phenanthroline-5,6-dione (phen-dione) ligand, one O atom from the nitrate anion and two O atoms from another phen-dione ligand. The coordination environment around silver is slightly distorted square-pyramidal. Inter-estingly, the Ag-O distances to the phen-dione ligand are different [Ag-O = 2.612?(6) and 2.470?(5)?Å]. The one-dimensional chains run parallel to [101] and are further inter-connected by weak hydrogen bonds (C-H?O) and ?-? stacking inter-actions [centroid-centroid distances 3.950?(4) and 3.792?(4)?Å], forming a three-dimensional supra-molecular network.

SUBMITTER: Jing X 

PROVIDER: S-EPMC3151901 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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catena-[[(nitrato-κO)silver(I)]-μ-1,10-phenanthroline-5,6-dione-κO,O':N,N'].

Jing Xiao X   Zhu Yu-Lan YL   Ma Kui-Rong KR   Cao Li L   Shao Shuai S  

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

In the title one-dimensional coordination polymer, [Ag(NO(3))(C(12)H(6)N(2)O(2))](n), the Ag(I) atom is penta-coordinated by two N atoms from a 1,10-phenanthroline-5,6-dione (phen-dione) ligand, one O atom from the nitrate anion and two O atoms from another phen-dione ligand. The coordination environment around silver is slightly distorted square-pyramidal. Inter-estingly, the Ag-O distances to the phen-dione ligand are different [Ag-O = 2.612 (6) and 2.470 (5) Å]. The one-dimensional chains run  ...[more]

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