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Tert-Butyl N-((1S)-2-hy-droxy-1-{N'-[(1E)-4-meth-oxy-benzyl-idene]hydrazinecarbon-yl}eth-yl)carbamate.

ABSTRACT: The mol-ecule of the title compound, C(16)H(23)N(3)O(5), is twisted about the chiral C atom, the dihedral angle formed between the amide residues being 79.6?(3)°. The conformation about the imine bond [1.278?(5)?Å] is E. In the crystal, O-H?O and N-H?O hydrogen bonding between the hy-droxy, amine and carbonyl groups leads to the formation of supra-molecular layers, which stack along the c-axis direction.

SUBMITTER: Pinheiro AC

PROVIDER: S-EPMC3151906 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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tert-Butyl N-((1S)-2-hy-droxy-1-{N'-[(1E)-4-meth-oxy-benzyl-idene]hydrazinecarbon-yl}eth-yl)carbamate.

Pinheiro Alessandra C AC de Souza Marcus V N MV Tiekink Edward R T ER Wardell Solange M S V SM Wardell James L JL

Acta crystallographica. Section E, Structure reports online 20110625 Pt 7

The mol-ecule of the title compound, C(16)H(23)N(3)O(5), is twisted about the chiral C atom, the dihedral angle formed between the amide residues being 79.6 (3)°. The conformation about the imine bond [1.278 (5) Å] is E. In the crystal, O-H⋯O and N-H⋯O hydrogen bonding between the hy-droxy, amine and carbonyl groups leads to the formation of supra-molecular layers, which stack along the c-axis direction. ...[more]

PMID: 21837178

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