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Poly[[hexa-aqua-bis-(?(3)-benzene-1,3,5-tricarboxyl-ato-?O:O:O)bis-(5,5'-dimethyl-2,2'-bipyridine-?N,N')trizinc] hexa-hydrate].

ABSTRACT: In the title compound, {[Zn(3)(C(9)H(3)O(6))(2)(C(12)H(12)N(2))(2)(H(2)O)(6)]·6H(2)O}(n), one Zn(II) atom, lying on an inversion center, is six-coordinated by two O atoms from two benzene-1,3,5-tricarboxyl-ate (btc) ligands and four water mol-ecules in a distorted octa-hedral geometry. The other Zn(II) atom is five-coordinated by two N atoms from a 5,5'-dimethyl-2,2'-bipyridine (dmbpy) ligand, two O atoms from two btc ligands and one water mol-ecule in a distorted trigonal-bipyramidal geometry. The compound features a one-dimensional ladder structure, with windows of ca 10.245?(1) × 15.446?(2)?Å. The ladders are linked together by inter-molecular O-H?O hydrogen bonds and ?-? inter-actions between the benzene rings and between the pyridine rings [centroid-to-centroid distances 3.858?(2) and 3.911?(3)?Å, respectively] to form a three-dimensional supra-molecular structure. One of the lattice water molecules is disordered over two positions in a 0.592:0.408 ratio.

SUBMITTER: Shan WW 

PROVIDER: S-EPMC3152031 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Poly[[hexa-aqua-bis-(μ(3)-benzene-1,3,5-tricarboxyl-ato-κO:O:O)bis-(5,5'-dimethyl-2,2'-bipyridine-κN,N')trizinc] hexa-hydrate].

Shan Wen-Wen WW   Xiong Han-Lin HL   Mei Chong-Zhen CZ  

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

In the title compound, {[Zn(3)(C(9)H(3)O(6))(2)(C(12)H(12)N(2))(2)(H(2)O)(6)]·6H(2)O}(n), one Zn(II) atom, lying on an inversion center, is six-coordinated by two O atoms from two benzene-1,3,5-tricarboxyl-ate (btc) ligands and four water mol-ecules in a distorted octa-hedral geometry. The other Zn(II) atom is five-coordinated by two N atoms from a 5,5'-dimethyl-2,2'-bipyridine (dmbpy) ligand, two O atoms from two btc ligands and one water mol-ecule in a distorted trigonal-bipyramidal geometry.  ...[more]

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