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Catena-Poly[[(2,2'-dimethyl-4,4'-bi-1,3-thia-zole-?N,N')cadmium]-di-?-bromido].


ABSTRACT: In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a 2,2'-dimethyl-4,4'-bi-1,3-thia-zole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure along [100]. Inter-chain C-H?Br hydrogen bonds and ?-? contacts between the thia-zole rings [centroid-centroid distances = 3.810?(5) and 3.679?(5)?Å] are observed.

SUBMITTER: Abedi A 

PROVIDER: S-EPMC3152112 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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catena-Poly[[(2,2'-dimethyl-4,4'-bi-1,3-thia-zole-κN,N')cadmium]-di-μ-bromido].

Abedi Anita A   Rezaei Forugh F  

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7


In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a 2,2'-dimethyl-4,4'-bi-1,3-thia-zole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure along [100]. Inter-chain C-H⋯Br hydrogen bonds and π-π contacts between the thia-zole rings [centroid-centroid distances = 3.810 (5) and 3.679 (5) Å] are observed. ...[more]

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