Unknown

Dataset Information

0

Bis(1-benzyl-3-methyl-imidazolium-?C)mercury(II) bis-(hexa-fluoridophosphate).


ABSTRACT: The asymmetric unit of the title complex, [Hg(C(11)H(12)N(2))(2)](PF(6))(2), consists of one bis-(1-benzyl-3-methyl-imidazolium)mercury(II) cation, one half of the cation and an additional Hg(II) atom, which lies on an inversion centre, and three hexa-fluorido-phosphate anions. The Hg(II) atoms exist in a linear coordination geometry [C-Hg-C = 178.9?(2) and 180°] formed by two carbene C atoms from the imidazole rings. In the crystal, the cations and anions are connected via C-H?F hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Haque RA 

PROVIDER: S-EPMC3200814 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

altmetric image

Publications

Bis(1-benzyl-3-methyl-imidazolium-κC)mercury(II) bis-(hexa-fluoridophosphate).

Haque Rosenani A RA   Salman Abbas Washeel AW   Hemamalini Madhukar M   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20110817 Pt 9


The asymmetric unit of the title complex, [Hg(C(11)H(12)N(2))(2)](PF(6))(2), consists of one bis-(1-benzyl-3-methyl-imidazolium)mercury(II) cation, one half of the cation and an additional Hg(II) atom, which lies on an inversion centre, and three hexa-fluorido-phosphate anions. The Hg(II) atoms exist in a linear coordination geometry [C-Hg-C = 178.9 (2) and 180°] formed by two carbene C atoms from the imidazole rings. In the crystal, the cations and anions are connected via C-H⋯F hydrogen bonds,  ...[more]

Similar Datasets

| S-EPMC3050194 | biostudies-literature
| S-EPMC2983204 | biostudies-literature
| S-EPMC2915252 | biostudies-literature
| S-EPMC3213513 | biostudies-other
| S-EPMC3588389 | biostudies-literature
| S-EPMC4257422 | biostudies-literature
| S-EPMC2971120 | biostudies-literature
| S-EPMC2983672 | biostudies-literature
| S-EPMC3515136 | biostudies-literature
| S-EPMC2970250 | biostudies-literature