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Dichlorido[3-meth-oxy-methyl-4-phenyl-5-(2-pyrid-yl)-4H-1,2,4-triazole-?N,N]copper(II).

ABSTRACT: In the title complex, [CuCl(2)(C(15)H(14)N(4)O)], the Cu(II) atom possesses a highly distorted square-planar geometry with N-Cu-N and Cl-Cu-Cl angles of 79.86?(8) and 98.65?(3)°, respectively, while the Cl-Cu-N angles fall into two distinct groups with values of 95.26?(6), 98.75?(6), 150.56?(6) and 152.04?(6)°. The pyridyl ring is twisted by 9.4?(2)° with respect to the triazole ring, which is oriented at approximately right angles [84.66?(8)°] with respect to the phenyl ring.

SUBMITTER: Cao S

PROVIDER: S-EPMC3200827 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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Dichlorido[3-meth-oxy-methyl-4-phenyl-5-(2-pyrid-yl)-4H-1,2,4-triazole-κN,N]copper(II).

Cao Shouping S Wang Zuoxiang Z Jin Xiaofei X

Acta crystallographica. Section E, Structure reports online 20110827 Pt 9

In the title complex, [CuCl(2)(C(15)H(14)N(4)O)], the Cu(II) atom possesses a highly distorted square-planar geometry with N-Cu-N and Cl-Cu-Cl angles of 79.86 (8) and 98.65 (3)°, respectively, while the Cl-Cu-N angles fall into two distinct groups with values of 95.26 (6), 98.75 (6), 150.56 (6) and 152.04 (6)°. The pyridyl ring is twisted by 9.4 (2)° with respect to the triazole ring, which is oriented at approximately right angles [84.66 (8)°] with respect to the phenyl ring. ...[more]

PMID: 22058873

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