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2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl.

ABSTRACT: The title compound, C(25)H(24)O(4), a meth-oxy-methyl (MOM) bis-protected BINOL derivative containing a methyl substituent in position 3, is a key inter-mediate for the synthesis of a great variety of chiral auxiliaries. The planes of the naphthyl aromatic rings are at an angle of 70.74?(3)°. There are no conventional hydrogen bonds binding the mol-ecules.

SUBMITTER: Carrilho RM

PROVIDER: S-EPMC3200832 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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2,2'-Bis(meth-oxy-meth-oxy)-3-methyl-1,1'-binaphth-yl.

Carrilho Rui M B RM Abreu Artur R AR Pereira Mariette M MM Rodrigues V H VH

Acta crystallographica. Section E, Structure reports online 20110817 Pt 9

The title compound, C(25)H(24)O(4), a meth-oxy-methyl (MOM) bis-protected BINOL derivative containing a methyl substituent in position 3, is a key inter-mediate for the synthesis of a great variety of chiral auxiliaries. The planes of the naphthyl aromatic rings are at an angle of 70.74 (3)°. There are no conventional hydrogen bonds binding the mol-ecules. ...[more]

PMID: 22058976

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