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1,2-Bis{[3,5-bis-(2,6-diisopropyl-phen-yl)phen-yl]imino}-acenaphthene toluene monosolvate.

ABSTRACT: In the title compound, C(72)H(80)N(2)·C(7)H(8), the acenaphthene ring system is essentially planar, with a maximum deviation of 0.041?(3)?Å. The benzene rings bonded to the the N atoms are essentially parallel, forming a dihedral angle of 0.80?(11)°, and these rings form dihedral angles of 87.49?(9) and 88.25?(10)° with the mean plane of the acenaphthene ring system. The methyl C atoms of three of the isopropyl groups are disordered of two sets of sites of equal occupancy.

SUBMITTER: Lohr TL

PROVIDER: S-EPMC3200865 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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1,2-Bis{[3,5-bis-(2,6-diisopropyl-phen-yl)phen-yl]imino}-acenaphthene toluene monosolvate.

Lohr Tracy L TL Piers Warren E WE Parvez Masood M

Acta crystallographica. Section E, Structure reports online 20110811 Pt 9

In the title compound, C(72)H(80)N(2)·C(7)H(8), the acenaphthene ring system is essentially planar, with a maximum deviation of 0.041 (3) Å. The benzene rings bonded to the the N atoms are essentially parallel, forming a dihedral angle of 0.80 (11)°, and these rings form dihedral angles of 87.49 (9) and 88.25 (10)° with the mean plane of the acenaphthene ring system. The methyl C atoms of three of the isopropyl groups are disordered of two sets of sites of equal occupancy. ...[more]

PMID: 22058927

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