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?-Acetato-diacetato{?-6,6'-dimethoxy-2,2'-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc.

ABSTRACT: In the heterodinuclear title complex, [GdZn(C(22)H(18)N(2)O(4))(CH(3)COO)(3)], the Zn(II) ion is five-coordinated in a square-pyramidal environment defined by two O atoms and two N atoms from the ligand, forming the square plane, and one acetate O atom serving as the apex, while the Gd(III) ion is nine-coordinated in an approximate mono-capped tetra-gonal-anti-prismatic environment defined by four O atoms from the ligand and five acetate O atoms.

SUBMITTER: Yang F

PROVIDER: S-EPMC3200867 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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μ-Acetato-diacetato{μ-6,6'-dimethoxy-2,2'-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc.

Yang Fan F Li Guang-Ming GM Chen Peng P Yan Peng-Fei PF Hou Guang-Feng GF

Acta crystallographica. Section E, Structure reports online 20110802 Pt 9

In the heterodinuclear title complex, [GdZn(C(22)H(18)N(2)O(4))(CH(3)COO)(3)], the Zn(II) ion is five-coordinated in a square-pyramidal environment defined by two O atoms and two N atoms from the ligand, forming the square plane, and one acetate O atom serving as the apex, while the Gd(III) ion is nine-coordinated in an approximate mono-capped tetra-gonal-anti-prismatic environment defined by four O atoms from the ligand and five acetate O atoms. ...[more]

PMID: 22058837

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