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(4,5-Diaza-fluoren-9-one-?N,N')bis-(1H-imidazole-?N)bis-(thio-cyanato-?N)cobalt(II).

ABSTRACT: In the title complex, [Co(NCS)(2)(C(3)H(4)N(2))(2)(C(11)H(6)N(2)O)], the Co(II) atom has a distorted octa-hedral coordination with the N atoms of the 4,5-diaza-fluoren-9-one ligand and two N atoms from imidazole ligands in the equatorial positions and the axial sites occupied by two N atoms of the thio-cyanate ligand. Inter-molecular N-H?O hydrogen bonding forms a one-dimensional motif parallel to the cell ab diagonal.

SUBMITTER: Feng XL

PROVIDER: S-EPMC3200902 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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(4,5-Diaza-fluoren-9-one-κN,N')bis-(1H-imidazole-κN)bis-(thio-cyanato-κN)cobalt(II).

Feng Xiu-Ling XL Zhang Yu-Ping YP

Acta crystallographica. Section E, Structure reports online 20110802 Pt 9

In the title complex, [Co(NCS)(2)(C(3)H(4)N(2))(2)(C(11)H(6)N(2)O)], the Co(II) atom has a distorted octa-hedral coordination with the N atoms of the 4,5-diaza-fluoren-9-one ligand and two N atoms from imidazole ligands in the equatorial positions and the axial sites occupied by two N atoms of the thio-cyanate ligand. Inter-molecular N-H⋯O hydrogen bonding forms a one-dimensional motif parallel to the cell ab diagonal. ...[more]

PMID: 22058833

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