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Tris(1,10-phenanthroline)iron(II) ?-oxido-bis-[trichloridoferrate(III)].

ABSTRACT: In the title salt, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O], the ionic components are linked into a two-dimensional supra-molecular layer by two pairs of C-H?Cl hydrogen bonds and ?-? stacking inter-actions [centroid-centroid distances = 3.655?(4) and 3.498?(3)?Å]. The salt is characterized as a mixed-valent Fe(II)-Fe(III) compound, in which an Fe(II) atom is coordinated by three phen ligands, forming a six-coordinated cationic entity and the anionic part is formed by two Fe(III) atoms in tetra-hedral coordination environments constructed by three chloride ions and one bridging oxide ligand. Intra-molecular C-H?N hydrogen bonds are observed.

SUBMITTER: Ling C

PROVIDER: S-EPMC3200904 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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Tris(1,10-phenanthroline)iron(II) μ-oxido-bis-[trichloridoferrate(III)].

Ling Chun C Song Li L Wang Xinping X

Acta crystallographica. Section E, Structure reports online 20110811 Pt 9

In the title salt, [Fe(C(12)H(8)N(2))(3)][Fe(2)Cl(6)O], the ionic components are linked into a two-dimensional supra-molecular layer by two pairs of C-H⋯Cl hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent Fe(II)-Fe(III) compound, in which an Fe(II) atom is coordinated by three phen ligands, forming a six-coordinated cationic entity and the anionic part is formed by two Fe(III) atoms in tetra-hedra ...[more]

PMID: 22065697

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