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{meso-Tetra-kis[p-(hept-yloxy)phen-yl]-porphyrinato}silver(II).

ABSTRACT: The title compound, [Ag(C(72)H(84)N(4)O(4))], crystallizes with the Ag(II) cation on a centre of symmetry. The macrocyclic 24-membered ring core is planar with a mean deviation of 0.0311?(15)?Å and the four-coordinate Ag(II) cation fits into its center, at 2.0814?(19) and 2.0872?(19)?Å, from the surrounding pyrrole-N atoms, in agreement with what is found in related compounds. The p-heptyl-oxyphenyl groups are rotated 75.51?(5) and 84.45?(8)° with respect to the porphyrin mean plane, due to steric hindrance with the pyrrole-H atoms of the macrocycle.

SUBMITTER: Liao JX

PROVIDER: S-EPMC3200905 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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{meso-Tetra-kis[p-(hept-yloxy)phen-yl]-porphyrinato}silver(II).

Liao Jun-Xu JX Zhao Hong-Bin HB Yang De-Liang DL Chen Liang L Wang Bang-Ying BY

Acta crystallographica. Section E, Structure reports online 20110827 Pt 9

The title compound, [Ag(C(72)H(84)N(4)O(4))], crystallizes with the Ag(II) cation on a centre of symmetry. The macrocyclic 24-membered ring core is planar with a mean deviation of 0.0311 (15) Å and the four-coordinate Ag(II) cation fits into its center, at 2.0814 (19) and 2.0872 (19) Å, from the surrounding pyrrole-N atoms, in agreement with what is found in related compounds. The p-heptyl-oxyphenyl groups are rotated 75.51 (5) and 84.45 (8)° with respect to the porphyrin mean plane, due to ster ...[more]

PMID: 22065718

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