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{2,2'-[(2,2-Dimethyl-propane-1,3-diyl-dinitrilo)-bis-(phenyl-methyl-idyne)]-diphenolato}nickel(II).

ABSTRACT: The asymmetric unit of the title complex, [Ni(C(31)H(28)N(2)O(2))], comprises two crystallographically independent mol-ecules. The geometry around the Ni(II) atom in each mol-ecule is distorted square planar. The dihedral angles between the two phen-oxy rings in each mol-ecule are 17.8?(4) and 36.5?(4)°. The crystal packing is stabilized by weak ?-? inter-actions [centroid-centroid distance = 3.758?(5)?Å] and C-H?? inter-actions.

SUBMITTER: Kargar H

PROVIDER: S-EPMC3200906 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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{2,2'-[(2,2-Dimethyl-propane-1,3-diyl-dinitrilo)-bis-(phenyl-methyl-idyne)]-diphenolato}nickel(II).

Kargar Hadi H Kia Reza R Moghadam Majid M Froozandeh Fatemeh F Tahir Muhammad Nawaz MN

Acta crystallographica. Section E, Structure reports online 20110802 Pt 9

The asymmetric unit of the title complex, [Ni(C(31)H(28)N(2)O(2))], comprises two crystallographically independent mol-ecules. The geometry around the Ni(II) atom in each mol-ecule is distorted square planar. The dihedral angles between the two phen-oxy rings in each mol-ecule are 17.8 (4) and 36.5 (4)°. The crystal packing is stabilized by weak π-π inter-actions [centroid-centroid distance = 3.758 (5) Å] and C-H⋯π inter-actions. ...[more]

PMID: 22065816

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