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A second monoclinic polymorph of bis-(2,2'-bipyridine-?N,N')diiodido-manganese(II).

ABSTRACT: The Mn(II) ion in the title complex, [MnI(2)(C(10)H(8)N(2))(2)], is six-coordinated in a distorted cis-N(4)I(2)Mn octa-hedral environment by four N atoms of the two chelating 2,2'-bipyridine ligands and two iodide anions. As a result of the different trans effects of the N and I atoms, the Mn-N bonds trans to the I atom are slightly longer than the Mn-N bonds trans to the N atom. The dihedral angle between the approximately planar ligands [maximum deviation = 0.064?(7)?Å] is 75.0?(1)°. Numerous inter- and intra-molecular ?-? inter-actions between the pyridyl rings are present, the shortest centroid-centroid distance being 3.905?(5)?Å. The structure reported herein represents a new monoclinic polymorph of the previously reported monoclinic (P2(1)/c) form [Ha (2011 ?). Z. Kristallogr. New Cryst. Struct.226, 187-188].

SUBMITTER: Ha K

PROVIDER: S-EPMC3201270 | biostudies-other | 2011 Oct

REPOSITORIES: biostudies-other

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A second monoclinic polymorph of bis-(2,2'-bipyridine-κN,N')diiodido-manganese(II).

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

The Mn(II) ion in the title complex, [MnI(2)(C(10)H(8)N(2))(2)], is six-coordinated in a distorted cis-N(4)I(2)Mn octa-hedral environment by four N atoms of the two chelating 2,2'-bipyridine ligands and two iodide anions. As a result of the different trans effects of the N and I atoms, the Mn-N bonds trans to the I atom are slightly longer than the Mn-N bonds trans to the N atom. The dihedral angle between the approximately planar ligands [maximum deviation = 0.064 (7) Å] is 75.0 (1)°. Numerous ...[more]

PMID: 22065514

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