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{5,5'-Bis(diethyl-amino)-2,2'-[(2,2-dimethyl-propane-1,3-di-yl)bis-(nitrilo-methanylyl-idene)]diphenolato}dioxido-molybdenum(VI).

ABSTRACT: In the title compound, [Mo(C(27)H(38)N(4)O(2))O(2)], the Mo(VI) atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetra-dentate Schiff base ligand in a distorted octa-hedral geometry. The Mo-N bond trans to a terminal oxide group is significantly longer than the other Mo-N bond, which is attributed to the strong trans effect of the oxide O atom. The dihedral angle formed between the substituted benzene rings is 71.79?(14)°. One of the ethyl groups is disordered over two sets of sites, with a refined site-occupancy ratio of 0.588?(18):0.412?(18).

SUBMITTER: Kargar H

PROVIDER: S-EPMC3201348 | biostudies-other | 2011 Oct

REPOSITORIES: biostudies-other

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{5,5'-Bis(diethyl-amino)-2,2'-[(2,2-dimethyl-propane-1,3-di-yl)bis-(nitrilo-methanylyl-idene)]diphenolato}dioxido-molybdenum(VI).

Kargar Hadi H Kia Reza R

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

In the title compound, [Mo(C(27)H(38)N(4)O(2))O(2)], the Mo(VI) atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetra-dentate Schiff base ligand in a distorted octa-hedral geometry. The Mo-N bond trans to a terminal oxide group is significantly longer than the other Mo-N bond, which is attributed to the strong trans effect of the oxide O atom. The dihedral angle formed between the substituted benzene rings is 71.79 (14)°. One of the ethyl groups is disordered over tw ...[more]

PMID: 22064844

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