Ontology highlight
ABSTRACT:
SUBMITTER: Lee JP
PROVIDER: S-EPMC3201448 | biostudies-other | 2011 Oct
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20110930 Pt 10
The homoleptic thio-ether title complex, [Ni(C(6)H(12)S(3))(2)](BF(4))(2)·2CH(3)NO(2), shows the expeced hexa-kis-(thio-ether) octa-hedral environment around the Ni(II) atom. It crystallized as two crystallographically independent complex cations, [Ni(9S3)(2)](2+) (9S3 = 1,4,7-trithia-cyclo-nona-ne), within the unit cell where each Ni(II) lies on an inversion center. In addition to the complex cations, there are two crystallographically independent BF(4) (-) anions present to balance the charge, ...[more]