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Acetyl-ferrocene-2-chloro-1-ferrocenyl-ethanone (1/1).

ABSTRACT: In the title co-crystal, [Fe(C(5)H(5))(C(7)H(6)ClO)][Fe(C(5)H(5))(C(7)H(7)O)], both substituted ferrocene mol-ecules show the expected sandwich structure. The crystal packing exhibits weak inter-molecular Cl?Cl contacts of 3.279?(4)?Å, ?-? inter-actions between the substituted Cp rings of two neighbouring 2-chloro-1-ferrocenyl-ethanone mol-ecules [centroid-centroid distance = 3.534?(3)?Å], and weak inter-molecular C-H?O and C-H?Cl hydrogen bonds.

SUBMITTER: Erben M

PROVIDER: S-EPMC3201489 | biostudies-other | 2011 Oct

REPOSITORIES: biostudies-other

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Acetyl-ferrocene-2-chloro-1-ferrocenyl-ethanone (1/1).

Erben Milan M Vinklárek Jaromír J Růžička Aleš A

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the title co-crystal, [Fe(C(5)H(5))(C(7)H(6)ClO)][Fe(C(5)H(5))(C(7)H(7)O)], both substituted ferrocene mol-ecules show the expected sandwich structure. The crystal packing exhibits weak inter-molecular Cl⋯Cl contacts of 3.279 (4) Å, π-π inter-actions between the substituted Cp rings of two neighbouring 2-chloro-1-ferrocenyl-ethanone mol-ecules [centroid-centroid distance = 3.534 (3) Å], and weak inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonds. ...[more]

PMID: 22058716

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