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Bis(3-benzoyl-1,1-di-sec-butyl-thio-ureato-?O,S)palladium(II).

ABSTRACT: The complex mol-ecule of the title complex, [Pd(C(16)H(23)N(2)OS)(2)], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The Pd(II) atom exists within a slightly distorted square-planar geometry defined by a cis-O(2)S(2) donor set. The dihedral angle formed between the mean planes of the symmetry-related six-membered chelate rings is 12.88?(7)° and the bond lengths within the rings are indicative of significant electron delocalization. In the crystal, mol-ecules aggregate into dimers linked by four C-H?O inter-actions.

SUBMITTER: Selvakumaran N

PROVIDER: S-EPMC3201548 | biostudies-other | 2011 Oct

REPOSITORIES: biostudies-other

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Bis(3-benzoyl-1,1-di-sec-butyl-thio-ureato-κO,S)palladium(II).

Selvakumaran N N Karvembu R R Ng Seik Weng SW Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20110917 Pt 10

The complex mol-ecule of the title complex, [Pd(C(16)H(23)N(2)OS)(2)], is completed by crystallographic twofold symmetry with the metal atom lying on the rotation axis. The Pd(II) atom exists within a slightly distorted square-planar geometry defined by a cis-O(2)S(2) donor set. The dihedral angle formed between the mean planes of the symmetry-related six-membered chelate rings is 12.88 (7)° and the bond lengths within the rings are indicative of significant electron delocalization. In the cryst ...[more]

PMID: 22058701

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