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Tetra-aqua-{1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole}sulfato-cobalt(II) dihydrate.

ABSTRACT: In the title complex, [Co(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Co(II) ion is six-coordinated by one N atom from a 1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole ligand, one O atom from a monodentate sulfate ligand and four water mol-ecules in a slightly distorted octa-hedral geometry. The sulfate ligand is rotationally disordered over two sets of sites with refined occupancies of 0.662?(15) and 0.338?(15). In the crystal, complex mol-ecules and solvent water mol-ecules are linked through inter-molecular O-H?O and O-H?N hydrogen bonds into a three-dimensional network.

SUBMITTER: Li YX

PROVIDER: S-EPMC3212154 | biostudies-other | 2011 Aug

REPOSITORIES: biostudies-other

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Tetra-aqua-{1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole}sulfato-cobalt(II) dihydrate.

Li Yu-Xian YX Li Da-Wei DW Zhao Dong D

Acta crystallographica. Section E, Structure reports online 20110713 Pt 8

In the title complex, [Co(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Co(II) ion is six-coordinated by one N atom from a 1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole ligand, one O atom from a monodentate sulfate ligand and four water mol-ecules in a slightly distorted octa-hedral geometry. The sulfate ligand is rotationally disordered over two sets of sites with refined occupancies of 0.662 (15) and 0.338 (15). In the crystal, complex mol-ecules and solvent water mol-ecules are linked t ...[more]

PMID: 22090856

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