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Poly[aqua-[?(5)-5-(isonicotinamido)-isophthalato][?(4)-5-(isonicotinamido)-isophthalato]cerium(III)silver(I)].


ABSTRACT: The 4d-4f heteronuclear title complex, [AgCe(C(14)H(8)N(2)O(5))(2)(H(2)O)](n), has a three-dimensional framework structure, generated by the carboxyl-ate and pyridyl groups of the 5-(isonicotinamido)-isophthalate (INAIP) ligands bridging the metal ions. The Ce(III) atom is coordinated by eight O atoms from six INAIP ligands and a water mol-ecule in a distorted tricapped trigonal-prismatic geometry, while the Ag(I) atom has a distorted trigonal-planar AgN(2)O geometry. O-H?O and N-H?O hydrogen bonds and ?-? inter-actions between the pyridine and benzene rings [centroid-centroid distances = 3.642?(4) and 3.624?(3)?Å] stabilize the crystal structure.

SUBMITTER: Nie X 

PROVIDER: S-EPMC3212176 | biostudies-other | 2011 Aug

REPOSITORIES: biostudies-other

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Poly[aqua-[μ(5)-5-(isonicotinamido)-isophthalato][μ(4)-5-(isonicotinamido)-isophthalato]cerium(III)silver(I)].

Nie Xue X   Qu Jing-Nian JN  

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8


The 4d-4f heteronuclear title complex, [AgCe(C(14)H(8)N(2)O(5))(2)(H(2)O)](n), has a three-dimensional framework structure, generated by the carboxyl-ate and pyridyl groups of the 5-(isonicotinamido)-isophthalate (INAIP) ligands bridging the metal ions. The Ce(III) atom is coordinated by eight O atoms from six INAIP ligands and a water mol-ecule in a distorted tricapped trigonal-prismatic geometry, while the Ag(I) atom has a distorted trigonal-planar AgN(2)O geometry. O-H⋯O and N-H⋯O hydrogen bo  ...[more]

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