Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Poly[[aqua-(?(7)-biphenyl-3,3',4,4'-tetra-carboxyl-ato)(1,10-phenanthroline)dicobalt(II)] monohydrate].

ABSTRACT: In the title compound, {[Co(2)(C(16)H(6)O(8))(C(12)H(8)N(2))(H(2)O)(2)]·H(2)O}(n), one Co(II) ion has a {CoN(2)O(4)} distorted octa-hedral environment defined by two N atoms of one 1,10-phenanthroline (phen) ligand, three O atoms of the carboxyl-ate groups of three biphenyl-3,3',4,4'-tetra-carboxyl-ate (BPTC) ligands, one of which is bidentate, and one O atom from one coordinated water mol-ecule. The other Co(II) atom is surrounded by six O atoms from four different BPTC ligands and one coordinated water mol-ecule. Each BPTC ligand forms eight coordination bonds with seven Co(II) atoms, leading to a layer structure along the ac plane. Uncoordinated water mol-ecules occupy the space between the layers, and inter-act via inter-layer O-H?O hydrogen bonds along the b axis, generating a three-dimensional supra-molecular network.

SUBMITTER: Yin H

PROVIDER: S-EPMC3212184 | biostudies-other | 2011 Aug

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Poly[[aqua-(μ(7)-biphenyl-3,3',4,4'-tetra-carboxyl-ato)(1,10-phenanthroline)dicobalt(II)] monohydrate].

Yin Hailiang H Yin Fengjuan F Lu Yukun Y

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8

In the title compound, {[Co(2)(C(16)H(6)O(8))(C(12)H(8)N(2))(H(2)O)(2)]·H(2)O}(n), one Co(II) ion has a {CoN(2)O(4)} distorted octa-hedral environment defined by two N atoms of one 1,10-phenanthroline (phen) ligand, three O atoms of the carboxyl-ate groups of three biphenyl-3,3',4,4'-tetra-carboxyl-ate (BPTC) ligands, one of which is bidentate, and one O atom from one coordinated water mol-ecule. The other Co(II) atom is surrounded by six O atoms from four different BPTC ligands and one coordina ...[more]

PMID: 22090886

Similar Datasets

Poly[(μ(3)-biphenyl-3,3'-dicarboxyl-ato)(1,10-phenanthroline)cadmium].

Project description:In the title compound, [Cd(C(14)H(8)O(4))(C(12)H(8)N(2))](n), the Cd(II) ion is seven-coordinated in a distorted penta-gonal-bipyramidal coordination geometry by five O atoms from bridging biphenyl-3,3'-dicarboylate (dpda) ligands and two N atoms from a 1,10-phenanthroline (1,10-phen) ligand. In the crystal, dinuclear units with a Cd⋯Cd separation of 3.8208 (7) Å are observed. Each of these dinuclear units is bridged via 3,3'-bpda in a chelating/chelating and bridging fashion, generating a zigzag chain along the c axis. Neighboring chains are further packed via weak π-π inter-actions between inter-chain parallel 1,10-phen rings [centroid-centroid distance = 3.5197 (9) Å] into a three-dimensional supra-molecular architecture.

| S-EPMC3246978 | biostudies-literature

catena-Poly[[aqua-(1,10-phenanthroline)cadmium(II)]-μ-benzene-1,4-di-carboxyl-ato].

Project description:The title compound, [Cd(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)](n), is a new coordination polymer of benzene-1,4-dicarboxyl-ate with cadmium(II) and 1,10-phenanthroline. The Cd(II) ion is coordinated by two N atoms from the 1,10-phenanthroline mol-ecule, three O atoms from two crystallographically independent benzene-1,4-dicarboxyl-ate ligands and the O atom of a coordinated water mol-ecule, forming a heavily distorted octa-hedron. The 1,10-phenanthroline ligand is approximately planar within 0.073 (4) Å. The two different benzene-1,4-dicarboxyl-ate ligands each coordinate to two Cd(II) ions in bidentate and monodentate modes, forming an infinite zigzag chain. Adjacent chains are packed tightly by strong π-π inter-actions [centroid-centroid distances = 3.851 (2) and 3.859 (2) Å] between the aromatic rings of the benzene-1,4-dicarboxyl-ate ligand and the 1,10-phenanthroline of a neighboring chain, forming a sheet parallel to (011). Different sheets are linked together via O-H⋯O hydrogen bonds between the coordinated water mol-ecules and the O atoms of the carboxyl-ate groups, forming a three-dimensional network.

| S-EPMC2967922 | biostudies-literature

Bis(4'-hy-droxy-biphenyl-4-carboxyl-ato-κO)(1,10-phenanthroline-κN,N')zinc.

Project description:In the title compound, [Zn(C(13)H(9)O(3))(2)(C(12)H(8)N(2))], the Zn(II) atom is located on a twofold rotation axis and has a distorted tetra-hedral coordination with two N atoms from the phenanthroline ligand arranged around the twofold axis and two O atoms from two symmetry-related 4'-hy-droxy-biphenyl-4-carboxyl-ate ligands. The mol-ecules are linked by O-H⋯O hydrogen bonds, forming a chain developing parallel to [101].

| S-EPMC3089091 | biostudies-literature

Aqua-(furan-2-carboxyl-ato-?O)(furan-2-carboxyl-ato-?O,O')(1,10-phenanthroline-?N,N')copper(II) methanol hemisolvate.

Project description:The asymmetric unit of the title compound, [Cu(C(5)H(3)O(3))(2)(C(12)H(8)N(2))(2)(H(2)O)]·0.5CH(3)OH, contains two Cu(II) complex mol-ecules and one methanol solvent mol-ecule with the metal centres in strongly distorted octahedral coordination. The coordinated water mol-ecule is involved in inter-molecular O-H?O hydrogen bonding, which links the complex mol-ecules into chains propagating along the c axis. Neighbouring chains inter-act further via ?-? inter-actions between the aromatic rings of 1,10-phenanthroline fragments [centroid-centroid distances = 3.726?(4) and 3.750?(4)?Å].

| S-EPMC2977238 | biostudies-literature

Poly[[tetra-aqua-(μ(6)-2,2'-diiodo-biphenyl-4,4',5,5'-tetra-carboxyl-ato)dizinc(II)] dihydrate].

Project description:In the title compound, {[Zn(2)(C(16)H(4)I(2)O(8))(H(2)O)(4)]·2H(2)O}(n), two crystallographically independent Zn(II) atoms are each located on a twofold rotation axis. Both Zn(II) atoms are in distorted octa-hedral coordination geometries: one is coordinated by six O atoms from four carboxyl-ate groups, while the other is coordinated by two carboxyl-ate groups and four water mol-ecules. The tetra-carboxyl-ate ligand mol-ecules connect the Zn(II) atoms, completing a three-dimensional metal-organic framework. O-H⋯O hydrogen bonds link the metal-organic framework with the uncoord-inated water mol-ecules.

| S-EPMC2960511 | biostudies-literature

Aqua-(hippurato)bis-(1,10-phenanthroline)cobalt(II) nitrate monohydrate.

Project description:In the title compound, [Co(C(9)H(8)NO(3))(C(12)H(8)N(2))(2)(H(2)O)]NO(3)·H(2)O, the Co(II) atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octa-hedral geometry. The uncoordinated O atom of the hippuric acid anion is involved in an intra-molecular hydrogen bond to the coordinated water mol-ecule. The crystal packing is stabilized by inter-molecular O-H?O hydrogen bonds involving the Hc anions, the coordinated water mol-ecule, the nitrate anion and the uncoordinated water mol-ecule.

| S-EPMC3009208 | biostudies-literature

Aqua-dinitrato(quioxalino[2,3-f][1,10]phenanthroline)nickel(II) monohydrate.

Project description:In the crystal of the title compound, [Ni(NO(3))(2)(C(18)H(10)N(4))(H(2)O)]·H(2)O, the Ni(II) ion is coordinated in a distorted octahedral geometry by two N atoms of the 1,10-phenanthroline moiety of the ligand, three O atoms from two nitrate anions and an O atom from one water mol-ecule. O-H⋯O hydrogen bonds between the coordinated and the solvent water molecules and between these water molecules and the nitrate O atoms help to establish the crystal packing.

| S-EPMC2969060 | biostudies-literature

Dimethyl 3,3'-di-meth-oxy-biphenyl-4,4'-di-carboxyl-ate.

Project description:In the title compound, C18H18O6, the biphenyl moiety is twisted with a dihedral angle of 29.11 (10)°. The carbometh-oxy groups form C-C-C-O torsion angles of -18.3 (3) and -27.7 (3)° with the attached rings, as a result of steric hindrances from the nearby meth-oxy groups. In the absence of stacking inter-actions and with no H⋯O contacts shorter than 2.7 Å, the packing is dominated by weaker van der Waals inter-actions.

| S-EPMC3998533 | biostudies-literature

catena-Poly[[[aqua-(1,10-phenanthroline-κ²N,N')zinc]-μ-acetyl-ene-dicarboxyl-ato-κ²O¹:O²] monohydrate].

Project description:In the title complex, {[Zn(C₄O₄)(C₁₂H₈N₂)(H₂O)]·H₂O}(n), the penta-coordinated Zn(II) ion is bound to two N atoms of the 1,10-phenanthroline ligand, two O atoms from two bridging acetyl-enedicarboxyl-ate anions and a water O atom in a distorted trigonal-bipyramidal geometry. The crystal structure is characterized by polymeric zigzag chains running parallel to [2-10] and is stabilized by O-H⋯O hydrogen bonds.

| S-EPMC3393169 | biostudies-literature

μ-Biphenyl-3,3',4,4'-tetra-carboxyl-ato-κO:O-bis-[triaqua-(2,2'-bipyridyl-κN,N')nickel(II)] hexa-hydrate.

Project description:The asymmetric unit of the title complex, [Ni(2)(C(16)H(6)O(8))(C(10)H(8)N(2))(2)(H(2)O)(6)]·6H(2)O, contains one Ni(II) atom, one 2,2'-bipyridine ligand, three coordinated water mol-ecules, one-half of a fully deprotonated biphenyl-3,3',4,4'-tetra-carboxyl-ate anion and three lattice water mol-ecules. The Ni(II) atom displays a distorted NiN(2)O(4) octa-hedral coordination formed by one carboxyl-ate O atom, three water O atoms and two N atoms of the chelating ligand. The complete biphenyl-3,3',4,4'-tetra-carboxyl-ate ligand displays inversion symmetry and links two symmetry-related Ni(II) atoms into a binuclear complex. Neighbouring complex mol-ecules are linked through O-H⋯O hydrogen bonds into a three-dimensional structure. Additional O-H⋯O hydrogen bonds between the lattice water mol-ecules help to consolidate the crystal packing.

| S-EPMC2977608 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data