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{N'-[(E)-1-(5-Bromo-2-oxidophen-yl)ethyl-idene-?O]-4-methyl-benzohydrazidato-?N',O}(pyridine-?N)nickel(II).

ABSTRACT: The central Ni(II) atom in the title complex, [Ni(C(16)H(13)BrN(2)O(2))(C(5)H(5)N)], is in a square-planar trans-N(2)O(2) environment defined by the NO(2) donor atoms of the tridentate hydrazone ligand and the monodentate pyridine ligand. The pyridine mol-ecule forms a dihedral angle of 9.99?(11)° with the least-squares plane through the NiN(2)O(2) atoms.

SUBMITTER: Zheng CZ

PROVIDER: S-EPMC3212192 | biostudies-other | 2011 Aug

REPOSITORIES: biostudies-other

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{N'-[(E)-1-(5-Bromo-2-oxidophen-yl)ethyl-idene-κO]-4-methyl-benzohydrazidato-κN',O}(pyridine-κN)nickel(II).

Zheng Chang-Zheng CZ Wang Liang L Liu Juan J Wang Yu-Jie YJ

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8

The central Ni(II) atom in the title complex, [Ni(C(16)H(13)BrN(2)O(2))(C(5)H(5)N)], is in a square-planar trans-N(2)O(2) environment defined by the NO(2) donor atoms of the tridentate hydrazone ligand and the monodentate pyridine ligand. The pyridine mol-ecule forms a dihedral angle of 9.99 (11)° with the least-squares plane through the NiN(2)O(2) atoms. ...[more]

PMID: 22090894

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{N'-[(E)-(5-Bromo-2-oxidophen-yl)(phen-yl)methyl-ene]benzohydrazidato}pyridine-nickel(II).

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