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Catena-Poly[tris(2,4,6-trimethyl-anilinium) [(tetrachloridocadmium)-?-chlorido]].

ABSTRACT: The asymmetric unit of the title compound, {(C(9)H(14)N)(3)[CdCl(5)]}(n), comprises three 2,4,6-trimethyl-aniline dications and one half of the [Cd(2)Cl(10)](6-) anion. The Cd atoms are each coordinated by six Cl atoms, with octa-hedra linked by bridging, apical Cl atoms, forming linear chains running parallel to the a axis. The trimethylanilinium cations form stacks between the chains of CdCl(6) octa-hedra.

SUBMITTER: Rong T 

PROVIDER: S-EPMC3212197 | biostudies-other | 2011 Aug

REPOSITORIES: biostudies-other

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catena-Poly[tris(2,4,6-trimethyl-anilinium) [(tetrachloridocadmium)-μ-chlorido]].

Rong Tao T  

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8

The asymmetric unit of the title compound, {(C(9)H(14)N)(3)[CdCl(5)]}(n), comprises three 2,4,6-trimethyl-aniline dications and one half of the [Cd(2)Cl(10)](6-) anion. The Cd atoms are each coordinated by six Cl atoms, with octa-hedra linked by bridging, apical Cl atoms, forming linear chains running parallel to the a axis. The trimethylanilinium cations form stacks between the chains of CdCl(6) octa-hedra. ...[more]

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