Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

A general strategy for synthesis of metal oxide nanoparticles attached on carbon nanomaterials.

ABSTRACT: We report a general strategy for synthesis of a large variety of metal oxide nanoparticles on different carbon nanomaterials (CNMs), including single-walled carbon nanotubes, multi-walled carbon nanotubes, and a few-layer graphene. The approach was based on the ?-? interaction between CNMs and modified aromatic organic ligands, which acted as bridges connecting metal ions and CNMs. Our methods can be applicable for a large variety of metal ions, thus offering a great potential application.

SUBMITTER: Zhao Y

PROVIDER: S-EPMC3212219 | biostudies-other | 2011

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

A general strategy for synthesis of metal oxide nanoparticles attached on carbon nanomaterials.

Zhao Yi Y Li Jiaxin J Wu Chuxin C Guan Lunhui L

Nanoscale research letters 20110112 1

We report a general strategy for synthesis of a large variety of metal oxide nanoparticles on different carbon nanomaterials (CNMs), including single-walled carbon nanotubes, multi-walled carbon nanotubes, and a few-layer graphene. The approach was based on the π-π interaction between CNMs and modified aromatic organic ligands, which acted as bridges connecting metal ions and CNMs. Our methods can be applicable for a large variety of metal ions, thus offering a great potential application. ...[more]

PMID: 21711580

Similar Datasets

General and controllable synthesis strategy of metal oxide/TiO2 hierarchical heterostructures with improved lithium-ion battery performance.

Project description:We demonstrate a simple, efficient, yet versatile strategy for the synthesis of novel hierarchical heterostructures composed of TiO(2) nanofiber stem and various metal oxides (MOs) secondary nanostructures, including Co(3)O(4), Fe(2)O(3), Fe(3)O(4), and CuO, by advantageously combining the versatility of the electrospinning technique and hydrothermal growth method, for which the controllable formation process and possible formation mechanism are also investigated. Moreover, as a proof-of-concept demonstration of the functional properties of these hierarchical heterostructures, the Co(3)O(4)/TiO(2) hierarchical heterostructures are investigated as the lithium-ion batteries (LIBs) anode materials for the first time, which not only delivers a high reversible capacity of 632.5 mAh g(-1) and 95.3% capacity retention over 480 cycles, but also shows excellent rate capability with respect to the pristine TiO(2) nanofibers. The synergetic effect between Co(3)O(4) and TiO(2) as well as the unique feature of hierarchical heterostructures are probably responsible for the enhanced electrochemical performance.

| S-EPMC3463005 | biostudies-literature

Reduced to Hierarchy: Carbon Filament-Supported Mixed Metal Oxide Nanoparticles.

Project description:We describe a one-pot synthesis method for carbon filament-supported mixed metal oxide nanoparticles. The thermal intracrystalline reaction of adamantanecarboxylate ions confined inside interlayer galleries of layered double hydroxide materials under a reducing atmosphere (H2) leads to carbon filaments forming in situ within the material. Raman spectroscopy and combined microscopy techniques show the formation of hybrid organic-inorganic carbon filaments with the mixed metal oxide particles interleaved.

| S-EPMC6893949 | biostudies-literature

General and programmable synthesis of hybrid liposome/metal nanoparticles.

Project description:Hybrid liposome/metal nanoparticles are promising candidate materials for biomedical applications. However, the poor selectivity and low yield of the desired hybrid during synthesis pose a challenge. We designed a programmable liposome by selective encoding of a reducing agent, which allows self-crystallization of metal nanoparticles within the liposome to produce stable liposome/metal nanoparticles alone. We synthesized seven types of liposome/monometallic and more complex liposome/bimetallic hybrids. The resulting nanoparticles are tunable in size and metal composition, and their surface plasmon resonance bands are controllable in visible and near infrared. Owing to outer lipid bilayer, our liposome/Au nanoparticle shows better colloidal stability in biologically relevant solutions as well as higher endocytosis efficiency than gold nanoparticles without the liposome. We used this hybrid in intracellular imaging of living cells via surface-enhanced Raman spectroscopy, taking advantage of its improved physicochemical properties. We believe that our method greatly increases the utility of metal nanoparticles in in vivo applications.

| S-EPMC5161430 | biostudies-literature

N-Dopant-Mediated Growth of Metal Oxide Nanoparticles on Carbon Nanotubes.

Project description:Metal oxide nanoparticles supported on heteroatom-doped graphitic surfaces have been pursued for several decades for a wide spectrum of applications. Despite extensive research on functional metal oxide nanoparticle/doped carbon nanomaterial hybrids, the role of the heteroatom dopant in the hybridization process of doped carbon nanomaterials has been overlooked. Here, the direct growth of MnOx and RuOx nanoparticles in nitrogen (N)-doped sites of carbon nanotubes (NCNTs) is presented. The quaternary nitrogen (NQ) sites of CNTs actively participate in the nucleation and growth of the metal nanoparticles. The evenly distributed NQ nucleation sites mediate the generation of uniformly dispersed <10 nm diameter MnOx and RuOx nanoparticles, directly decorated on NCNT surfaces. The electrochemical performance of the resultant hybridized materials was evaluated using cyclic voltammetry. This novel hybridization method using the dopant-mediated nucleation and growth of metal oxides suggests ways that heteroatom dopants can be utilized to optimize the structure, interface and corresponding properties of graphitic carbon-based hybrid materials.

| S-EPMC8400905 | biostudies-literature

General, Metal-free Synthesis of Carbon Nanofiber Assemblies from Plant Oils.

Project description:We designed a metal-free synthesis of carbon nanofiber based on ketene chemistry using phosphorus pentoxide (P2 O5 ) and vegetable oil. Based on the characterization of intermediates, P2 O5 -oil reaction yielded most possibly alkylketenes, which polymerized into poly(ketene) with abundant enol groups. The enol groups further reacted with P2 O5 , forcing the poly(ketene) to assemble into a nano-sized preassembly structure. Moderate heating transforms these structures into carbonaceaus nanofibers. This approach is applicable to other chemicals with similar structure to vegetable oil. The carbon nanofibers with P-O-C functionalization show relatively high graphitization degree and promising textural properties. The C-O-P environment accounts for 66 at % of the total P and creates a superior thermal stability. As a model application, a CDI system built of a carbon-nanofiber-based electrode countered by an activated carbon-based electrode exhibited exceptional performance.

| S-EPMC8596426 | biostudies-literature

Metal-Organic Frameworks to Metal/Metal Oxide Embedded Carbon Matrix: Synthesis, Characterization and Gas Sorption Properties.

Project description:Three isostructural metal-organic frameworks, (MOFs), [Fe(OH)(1,4-NDC)] (1), [Al(OH)(1,4-NDC)] (2), and [In(OH)(1,4-NDC)] (3) have been synthesized hydrothermally by using 1,4-naphthalene dicarboxylate (1,4-NDC) as a linker. The MOFs were characterized using various techniques and further used as precursor materials for the synthesis of metal/metal oxide nanoparticles inserted in a carbon matrix through a simple thermal conversion method. The newly synthesized carbon materials were characterized by scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy analysis, powder X-ray diffraction and BET analysis. The results showed that the MOF-derived carbon composite materials maintained the morphology of the original MOF upon carbonization, and confirmed the insertion of metal/metal oxide particles in the carbon matrix.

| S-EPMC5455493 | biostudies-literature

Metal oxide nanoparticles embedded in porous carbon for sulfur absorption under hydrothermal conditions.

Project description:MOx (M = Zn, Cu, Mn, Fe, Ce) nanoparticles (NPs) embedded in porous C with uniform diameter and dispersion were synthesized, with potential application as S-absorbents to protect catalysts from S-poisoning in catalytic hydrothermal gasification (cHTG) of biomass. S-absorption performance of MOx/C was evaluated by reacting the materials with diethyl disulfide at HTG conditions (450 °C, 30 MPa, 15 min). Their S-absorption capacity followed the order CuOx/C > CeOx/C ≈ ZnO/C > MnOx/C > FeOx/C. S was absorbed in the first four through the formation of Cu1.8S, Ce2S3, ZnS, and MnS, respectively, with a capacity of 0.17, 0.12, 0.11, and 0.09 molS molM-1. The structure of MOx/C (M = Zn, Cu, Mn) evolved significantly during S-absorption reaction, with the formation of larger agglomerates and separation of MOx particles from porous C. The formation of ZnS NPs and their aggregation in place of hexagonal ZnO crystals indicate a dissolution/precipitation mechanism. Note that aggregated ZnS NPs barely sinter under these conditions. Cu(0) showed a preferential sulfidation over Cu2O, the sulfidation of the latter seemingly following the same mechanism as for ZnO. In contrast, FeOx/C and CeOx/C showed remarkable structural stability with their NPs well-dispersed within the C matrix after reaction. MOx dissolution in water (from liquid to supercritical state) was modeled and a correlation between solubility and particle growth was found, comforting the hypothesis of the importance of an Ostwald ripening mechanism. CeOx/C with high structural stability and promising S-absorption capacity was suggested as a promising bulk absorbent for sulfides in cHTG of biomass.

| S-EPMC10282018 | biostudies-literature

Chemical Simultaneous Synthesis Strategy of Two Nitrogen-Rich Carbon Nanomaterials for All-Solid-State Symmetric Supercapacitor.

Project description:Present work demonstrates a single step process for simultaneous synthesis of metal-nanoparticle-encapsulated nitrogen-doped bamboo-shaped carbon nanotubes (M/N-BCNTs) and graphitic carbon nitride (G-C3N3). The synthesis of two different carbon nanostructures in a single step is recognized for the first time. This process involves the use of inexpensive and nontoxic precursors such as melamine as carbon and nitrogen sources for the growth of G-C3N3 and M/N-BCNTs. In this technique, the utilization of unwanted gases such as ammonia and hydrocarbons released during the decomposition of melamine is the key to grow M/N-BCNTs over the catalyst along with the formation of G-C3N4. The implementation of M/N-BCNTs as the electrode material for all-solid-state symmetric supercapacitor results in a maximum specific capacitance of ∼368 F g-1 with excellent electrochemical stability with 97% capacity retention after 10 000 cycles. Furthermore, fabricated symmetric supercapacitor shows maximum high energy and power density up to 10.88 W h kg-1 and 2.06 kW kg-1, respectively. The superior electrochemical activity of M/N-BCNTs can be attributed to its high surface to area volume ratio, unique structural characteristics, ultrahigh electrical conductivity, and carrier mobility.

| S-EPMC6644270 | biostudies-literature

Synthesis of Aluminum-Based Metal-Organic Framework (MOF)-Derived Carbon Nanomaterials and Their Water Adsorption Isotherm.

Project description:The characteristics of water vapor adsorption depend on the structure, porosity, and functional groups of the material. Metal-organic framework (MOF)-derived carbon (MDC) is a novel material that exhibits a high specific area and tunable pore sizes by exploiting the stable structure and porosity of pure MOF materials. Herein, two types of aluminum-based MOFs were used as precursors to synthesize hydrophobic microporous C-MDC and micro-mesoporous A-MDC via carbonization and activation depending on the type of ligands in the precursors. C-MDC and A-MDC have different pore characteristics and exhibit distinct water adsorption properties. C-MDC with hydrophobic properties and micropores exhibited negligible water adsorption (108.54 mgg-1) at relatively low pressures (P/P0~0.3) but showed a rapid increase in water adsorption ability (475.7 mgg-1) at relative pressures of about 0.6. A comparison with the isotherm model indicated that the results were consistent with the theories, which include site filling at low relative pressure and pore filling at high relative pressure. In particular, the Do-Do model specialized for type 5 showed excellent agreement.

| S-EPMC10458837 | biostudies-literature

A general soft-enveloping strategy in the templating synthesis of mesoporous metal nanostructures.

Project description:Metal species have a relatively high mobility inside mesoporous silica; thus, it is difficult to introduce the metal precursors into silica mesopores and suppress the migration of metal species during a reduction process. Therefore, until now, the controlled growth of metal nanocrystals in a confined space, i.e., mesoporous channels, has been very challenging. Here, by using a soft-enveloping reaction at the interfaces of the solid, liquid, and solution phases, we successfully control the growth of metallic nanocrystals inside a mesoporous silica template. Diverse monodispersed nanostructures with well-defined sizes and shapes, including Ag nanowires, 3D mesoporous Au, AuAg alloys, Pt networks, and Au nanoparticle superlattices are successfully obtained. The 3D mesoporous AuAg networks exhibit enhanced catalytic activities in an electrochemical methanol oxidation reaction. The current soft-enveloping synthetic strategy offers a robust approach to synthesize diverse mesoporous metal nanostructures that can be utilized in catalysis, optics, and biomedicine applications.

| S-EPMC5802826 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data