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Poly[bis-[?-1,4-bis-(imidazol-1-ylmeth-yl)benzene]-dichloridomanganese(II)].

ABSTRACT: In the crystal structure of the title compound, [MnCl(2)(C(14)H(14)N(4))(2)](n), the Mn(II) atom, lying on an inversion center, is coordinated by four N atoms from four 1,4-bis-(imidazol-1-ylmeth-yl)benzene (bimb) ligands and two Cl(-) anions in a distorted octa-hedral geometry. The bimb ligands bridge the Mn(II) atoms, forming a two-dimensional polymeric complex, which is composed of a 52-membered [Mn(4)(bimb)(4)] ring with distances of 7.7812?(2) and 27.4731?(9)?Å between opposite metal atoms. Weak C-H?? inter-actions are present in the crystal structure.

SUBMITTER: Mei CZ

PROVIDER: S-EPMC3212256 | biostudies-other | 2011 Aug

REPOSITORIES: biostudies-other

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Poly[bis-[μ-1,4-bis-(imidazol-1-ylmeth-yl)benzene]-dichloridomanganese(II)].

Mei Chong-Zhen CZ Shan Wen-Wen WW Li Kai-Hui KH

Acta crystallographica. Section E, Structure reports online 20110730 Pt 8

In the crystal structure of the title compound, [MnCl(2)(C(14)H(14)N(4))(2)](n), the Mn(II) atom, lying on an inversion center, is coordinated by four N atoms from four 1,4-bis-(imidazol-1-ylmeth-yl)benzene (bimb) ligands and two Cl(-) anions in a distorted octa-hedral geometry. The bimb ligands bridge the Mn(II) atoms, forming a two-dimensional polymeric complex, which is composed of a 52-membered [Mn(4)(bimb)(4)] ring with distances of 7.7812 (2) and 27.4731 (9) Å between opposite metal atoms. ...[more]

PMID: 22090913

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