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Tetra-aqua-bis-{2-[4-(4-pyrid-yl)pyrimidin-2-ylsulfan-yl]acetato}-zinc.

ABSTRACT: In the title compound, [Zn(C(11)H(8)N(3)O(2)S)(2)(H(2)O)(4)], the Zn(II) ion lies on an inversion centre and is coordinated by four water mol-ecules and two N atoms from two 2-[4-(4-pyrid-yl)pyrimidin-2-ylsulfan-yl]acetate (L) ligands in a distorted octa-hedral geometry. In L, the pyridine and pyrimidine rings are twisted at an angle of 11.2?(1)°. The coordinated water mol-ecules and the acetate groups are involved in the formation of a three-dimensional hydrogen-bonded network, which consolidates the crystal packing.

SUBMITTER: Zhu HB

PROVIDER: S-EPMC3212265 | biostudies-other | 2011 Aug

REPOSITORIES: biostudies-other

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Tetra-aqua-bis-{2-[4-(4-pyrid-yl)pyrimidin-2-ylsulfan-yl]acetato}-zinc.

Zhu Hai-Bin HB Lu Xin X

Acta crystallographica. Section E, Structure reports online 20110730 Pt 8

In the title compound, [Zn(C(11)H(8)N(3)O(2)S)(2)(H(2)O)(4)], the Zn(II) ion lies on an inversion centre and is coordinated by four water mol-ecules and two N atoms from two 2-[4-(4-pyrid-yl)pyrimidin-2-ylsulfan-yl]acetate (L) ligands in a distorted octa-hedral geometry. In L, the pyridine and pyrimidine rings are twisted at an angle of 11.2 (1)°. The coordinated water mol-ecules and the acetate groups are involved in the formation of a three-dimensional hydrogen-bonded network, which consolidat ...[more]

PMID: 22090922

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