Browse
Submit Data
Databases
API
Help

Dataset Information

11 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

1-Chloro-1-[(4-methyl-phen-yl)hydrazinyl-idene]propan-2-one.

ABSTRACT: The asymmetric unit of the title compound, C(10)H(11)ClN(2)O, contains two mol-ecules. The non-H atoms of each mol-ecule lie approximately on a plane (r.m.s. deviations = 0.062 and 0.110?Å), and the C=N double bond has a Z-configuration in both independent mol-ecules. In the crystal, adjacent mol-ecules are linked by N-H?O(carbon-yl) hydrogen bonds, forming chains running along [100].

SUBMITTER: Asiri AM

PROVIDER: S-EPMC3212346 | biostudies-other | 2011 Aug

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

1-Chloro-1-[(4-methyl-phen-yl)hydrazinyl-idene]propan-2-one.

Asiri Abdullah M AM Al-Youbi Abdulrahman O AO Zayed Mohie E M ME Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110709 Pt 8

The asymmetric unit of the title compound, C(10)H(11)ClN(2)O, contains two mol-ecules. The non-H atoms of each mol-ecule lie approximately on a plane (r.m.s. deviations = 0.062 and 0.110 Å), and the C=N double bond has a Z-configuration in both independent mol-ecules. In the crystal, adjacent mol-ecules are linked by N-H⋯O(carbon-yl) hydrogen bonds, forming chains running along [100]. ...[more]

PMID: 22091003

Similar Datasets

1-Chloro-1-[(4-chloro-phen-yl)hydrazinyl-idene]propan-2-one.

Project description:The non-H atoms of the title compound, C(9)H(8)Cl(2)N(2)O, lie nearly on a plane (r.m.s. deviation = 0.110?Å), and the C=N double bond has a Z configuration. In the crystal, adjacent mol-ecules are linked by an N-H?O(carbon-yl) hydrogen bond, forming a chain running along [100].

| S-EPMC3212344 | biostudies-literature

1-Chloro-1-[(4-nitro-phen-yl)hydrazinyl-idene]propan-2-one.

Project description:The non-H atoms of the title compound, C(9)H(8)ClN(3)O(3), lie approximately on a plane (r.m.s. deviation = 0.111?Å), and the C=N double bond has a Z configuration. In the crystal, adjacent mol-ecules are linked by an N-H?O(carbon-yl) hydrogen bond, forming a chain running along [101].

| S-EPMC3212345 | biostudies-literature

1-Chloro-1-[(4-meth-oxy-phen-yl)hydrazinyl-idene]propan-2-one.

Project description:The non-H atoms of the title compound, C(10)H(11)ClN(2)O(2), lie nearly on a plane (r.m.s. deviation = 0.150?Å), and the C=N double bond has a Z configuration. In the crystal, adjacent mol-ecules are linked by an N-H?O(carbon-yl) hydrogen bond, forming a chain running along [201].

| S-EPMC3212343 | biostudies-literature

(Z)-1-Chloro-1-[2-(2-nitro-phen-yl)hydrazinyl-idene]propan-2-one.

Project description:The title mol-ecule, C9H8ClN3O3, lies on a mirror plane. Intra-molecular N-H?O and N-H?Cl hydrogen bonds occur. One of the nitro O atoms is disordered (site occupancy ratio = 0.40:0.10).

| S-EPMC3588268 | biostudies-literature

4-[2-(4-Chloro-phen-yl)hydrazinyl-idene]-3-methyl-1H-pyrazol-5(4H)-one.

Project description:In the title compound, C(10)H(9)ClN(4)O, the pyrazole ring [maximum deviation = 0.014?(2)?Å] forms a dihedral angle of 7.06?(14)° with the chloro-benzene ring. The mol-ecular conformation is stabilized by an intra-molecular N-H?O hydrogen bond, which generates an S(6) ring motif. In the crystal, inversion dimers linked by pairs of C-H?O hydrogen bonds generate R(2) (2)(16) ring motifs. The dimers are further connected by N-H?N hydrogen bonds, thereby forming layers lying parallel to the bc plane.

| S-EPMC3201479 | biostudies-literature

(3-Chloro-phen-yl)[(E)-2-(1,3-di-thio-lan-2-yl-idene)hydrazinyl-idene]methyl 3-chloro-benzoate.

Project description:In the title compound, C17H12Cl2N2O2S2, the di-thia-cyclo-pentane ring has an envelope conformation with one of the methyl-ene C atoms as the flap. The chloro-phenyl rings make a dihedral angle of 82.63?(7)°. In the crystal, ?-? inter-actions between the benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.547?(2)?Å] link the mol-ecules into inversion dimers. Weak non-classical C-H?X (X = O, N, Cl) inter-actions further consolidate the packing, forming a layer structure parallel to (110).

| S-EPMC3648247 | biostudies-literature

(Z)-Ethyl 2-chloro-2-[2-(4-methyl-phen-yl)hydrazinyl-idene]acetate.

Project description:The mol-ecule of the title compound, C11H13ClN2O2, is approximately planar (r.m.s. deviation = 0.099?Å for non-H atoms) and adopts a Z conformation about the C=N double bond. In the crystal, mol-ecules are linked by N-H?O and C-H?O hydrogen bonds to the same O-atom acceptor, forming zigzag chains propagating along [010]. These inter-actions give rise to R2(1)(6) loops.

| S-EPMC3589004 | biostudies-literature

(Z)-4-[2-(2,4-Dimethyl-phen-yl)hydrazinyl-idene]-3-methyl-pyrazol-5(1H)-one.

Project description:The mol-ecule of the title compound, C12H14N4O, is roughly planar, with a dihedral angle of 8.0?(8)° between the benzene and pyrazole rings, and an intra-molecular N-H?O hydrogen bond forms an S(6) ring motif. In the crystal, mol-ecules are linked into an inversion dimer by a pair of N-H?O hydrogen bonds, which form an R 2 (2)(8) ring motif.

| S-EPMC3629586 | biostudies-literature

4-{[2-(2,4-Dinitro-phen-yl)hydrazinyl-idene](phen-yl)meth-yl}-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol monosolvate.

Project description:In the title compound, C23H18N6O5·C2H6O, all three benzene rings lie in an approximate plane [maximum deviation = 0.2688 (16) Å] that makes an angle of 53.56 (3)° with the plane of the pyrazolone ring. Intra-molecular N-H⋯O hydrogen bonds occur. In the crystal, the ethanol solvent mol-ecule links adjacent mol-ecules through N-H⋯O-H⋯O hydrogen bonds, leading to an infinite chain along the c-axis direction. The ethyl group of the ethanol solvent mol-ecule is disordered over two set of sites in a 0.762 (5):0.238 (5) ratio.

| S-EPMC3588976 | biostudies-literature

3-{1-[2-(2-Chloro-phen-yl)hydrazinyl-idene]-2,2,2-trifluoro-eth-yl}-7-diethyl-amino-2H-chromen-2-one.

Project description:The title compound, C(21)H(19)ClF(3)N(3)O(2), has a structure related to other coumarin derivatives that have been used as fluorescent probes of metal ions. The dihedral angle between the coumarin ring system and the chlorobenzene ring is 42.99?(9)°. Intra-molecular hydrogen bonding occurs via N-H?O and N-H?Cl inter-actions, generating S(7) and S(5) rings, respectively. The crystal packing is stabilized by weak C-H?O hydrogen bonds.

| S-EPMC3200584 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data