Unknown

Dataset Information

0

Bis(8-hy-droxy-1-methyl-quinolin-1-ium) bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II) dihydrate.


ABSTRACT: In the title ion-pair complex, (C(10)H(10)NO)(2)[Ni(C(4)N(2)S(2))(2)]·2H(2)O, the anion has crystallographically imposed centre of symmetry. The Ni(II) atom exhibits a slightly distorted square-planar coordination geometry. In the crystal, the water mol-ecule links anions and cations into a three-dimensional network via O-H?N, O-H?S and O-H?O hydrogen bonds. The structure is further stabilized by weak S?? contacts [S?centroid = 3.8047?(9)?Å] and ?-? stacking inter-actions [centriod-centroid distance = 3.8653?(7)?Å].

SUBMITTER: Guan ZH 

PROVIDER: S-EPMC3238595 | biostudies-other | 2011 Dec

REPOSITORIES: biostudies-other

altmetric image

Publications

Bis(8-hy-droxy-1-methyl-quinolin-1-ium) bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II) dihydrate.

Guan Zhi-Heng ZH   Jiang Zhang Z   Wang Fang-Ming FM  

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12


In the title ion-pair complex, (C(10)H(10)NO)(2)[Ni(C(4)N(2)S(2))(2)]·2H(2)O, the anion has crystallographically imposed centre of symmetry. The Ni(II) atom exhibits a slightly distorted square-planar coordination geometry. In the crystal, the water mol-ecule links anions and cations into a three-dimensional network via O-H⋯N, O-H⋯S and O-H⋯O hydrogen bonds. The structure is further stabilized by weak S⋯π contacts [S⋯centroid = 3.8047 (9) Å] and π-π stacking inter-actions [centriod-centroid dist  ...[more]

Similar Datasets

| S-EPMC3246985 | biostudies-literature
| S-EPMC3050285 | biostudies-literature
| S-EPMC3152075 | biostudies-literature
| S-EPMC2977634 | biostudies-literature
| S-EPMC3120553 | biostudies-literature
| S-EPMC3435580 | biostudies-literature
| S-EPMC3238640 | biostudies-literature
| S-EPMC2961888 | biostudies-other
| S-EPMC3212183 | biostudies-other
| S-EPMC3343807 | biostudies-other