Ontology highlight
ABSTRACT:
SUBMITTER: Guan ZH
PROVIDER: S-EPMC3238595 | biostudies-other | 2011 Dec
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20111105 Pt 12
In the title ion-pair complex, (C(10)H(10)NO)(2)[Ni(C(4)N(2)S(2))(2)]·2H(2)O, the anion has crystallographically imposed centre of symmetry. The Ni(II) atom exhibits a slightly distorted square-planar coordination geometry. In the crystal, the water mol-ecule links anions and cations into a three-dimensional network via O-H⋯N, O-H⋯S and O-H⋯O hydrogen bonds. The structure is further stabilized by weak S⋯π contacts [S⋯centroid = 3.8047 (9) Å] and π-π stacking inter-actions [centriod-centroid dist ...[more]