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Catena-Poly[[triphenyl-tin(IV)]-?-3-methyl-phenyl-seleninato-?O:O'].

ABSTRACT: In the polymeric title coordination compound, [Sn(C(6)H(5))(3)(C(7)H(7)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms from two symmetry-related bridging seleninate ligands in axial positions and three phenyl groups in the equatorial plane. In the crystal, the complex exhibits a zigzag chain structure running parallel to the c axis. An intra-chain C-H?O hydrogen bond is observed.

SUBMITTER: Ru J

PROVIDER: S-EPMC3238714 | biostudies-other | 2011 Dec

REPOSITORIES: biostudies-other

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catena-Poly[[triphenyl-tin(IV)]-μ-3-methyl-phenyl-seleninato-κO:O'].

Ru Jing J Zhang Rufen R

Acta crystallographica. Section E, Structure reports online 20111123 Pt 12

In the polymeric title coordination compound, [Sn(C(6)H(5))(3)(C(7)H(7)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms from two symmetry-related bridging seleninate ligands in axial positions and three phenyl groups in the equatorial plane. In the crystal, the complex exhibits a zigzag chain structure running parallel to the c axis. An intra-chain C-H⋯O hydrogen bond is observed. ...[more]

PMID: 22199591

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