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(Z)-2-(5-Chloro-2-oxoindolin-3-yl-idene)-N-phenyl-hydrazinecarbothio-amide.

ABSTRACT: In the title compound, C(15)H(11)ClN(4)OS, the dihedral angle between the nine-membered 5-chloro-indolin-2-one ring system and the benzene ring is 10.00?(6)°. Intra-molecular cyclic N-H?O and C-H?S hydrogen-bonding inter-actions [graph set S(6)] are present in the N-N-C-N chain between the ring systems. In the crystal, mol-ecules form centrosymmetric cyclic dimers through inter-molecular N-H?O hydrogen bonds [graph-set R(2) (2)(8)] and are extended by C-H?Cl inter-actions into infinite chains which propagate along [100].

SUBMITTER: Qasem Ali A

PROVIDER: S-EPMC3238816 | biostudies-other | 2011 Dec

REPOSITORIES: biostudies-other

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(Z)-2-(5-Chloro-2-oxoindolin-3-yl-idene)-N-phenyl-hydrazinecarbothio-amide.

Qasem Ali Amna A Eltayeb Naser Eltaher NE Teoh Siang Guan SG Salhin Abdussalam A Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20111102 Pt 12

In the title compound, C(15)H(11)ClN(4)OS, the dihedral angle between the nine-membered 5-chloro-indolin-2-one ring system and the benzene ring is 10.00 (6)°. Intra-molecular cyclic N-H⋯O and C-H⋯S hydrogen-bonding inter-actions [graph set S(6)] are present in the N-N-C-N chain between the ring systems. In the crystal, mol-ecules form centrosymmetric cyclic dimers through inter-molecular N-H⋯O hydrogen bonds [graph-set R(2) (2)(8)] and are extended by C-H⋯Cl inter-actions into infinite chains wh ...[more]

PMID: 22199669

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(Z)-2-(5-Chloro-2-oxoindolin-3-yl-idene)-N-methyl-hydrazinecarbothio-amide.

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(2E)-N-Methyl-2-[(2E)-3-phenyl-prop-2-en-1-yl-idene]hydrazinecarbothio-amide.

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