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(E)-1-(2,4-Dinitro-phen-yl)-2-[1-(2-meth-oxy-phen-yl)ethyl-idene]hydrazine.

ABSTRACT: The mol-ecule of the title compound, C(15)H(14)N(4)O(5), is in an E conformation with respect to the C=N double bond and the dihedral angle between the two benzene rings is 37.83?(7)°. The ethyl-idenehydrazine plane makes dihedral angles of 4.93?(9) and 42.38?(9)° with the two benzene rings. An intra-molecular N-H?O hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked by weak C-H?O inter-actions into chains along the c axis which are stacked along the b axis by aromatic ?-? inter-actions with a centroid-centroid distance of 3.5927?(10)?Å.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3238869 | biostudies-other | 2011 Dec

REPOSITORIES: biostudies-other

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(E)-1-(2,4-Dinitro-phen-yl)-2-[1-(2-meth-oxy-phen-yl)ethyl-idene]hydrazine.

Fun Hoong-Kun HK Nilwanna Boonlerd B Jansrisewangwong Patcharaporn P Kobkeatthawin Thawanrat T Chantrapromma Suchada S

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

The mol-ecule of the title compound, C(15)H(14)N(4)O(5), is in an E conformation with respect to the C=N double bond and the dihedral angle between the two benzene rings is 37.83 (7)°. The ethyl-idenehydrazine plane makes dihedral angles of 4.93 (9) and 42.38 (9)° with the two benzene rings. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked by weak C-H⋯O inter-actions into chains along the c axis which are stacked along the b axis by aroma ...[more]

PMID: 22199722

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