Unknown

Dataset Information

0

N,N'-Dibenzyl-N,N'-dimethyl-N''-(p-tol-yl)phospho-ric triamide.

ABSTRACT: The asymmetric unit of the title compound, C(23)H(28)N(3)OP, contains two independent mol-ecules with significant conformational differences. For example, the torsion angles N-C-C-C involving the N-benzyl moieties are 57.3?(7) and 11.6?(8)° in one mol-ecule and 76.5?(7) and 97.4?(7)° in the other. In each mol-ecule, the P atom exhibits a distorted tetra-hedral conformation [the bond angles at P are in the ranges 104.7?(2)-115.2?(2) and 105.1?(2)-115.1?(2)° in the two molecules], and the phosphoryl group and the N-H group adopt an anti orientation with respect to one another. In the crystal, mol-ecules are linked via N-H?O(P) hydrogen bonds, forming a chain parallel to the a axis.

SUBMITTER: Pourayoubi M 

PROVIDER: S-EPMC3238883 | biostudies-other | 2011 Dec

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

N,N'-Dibenzyl-N,N'-dimethyl-N''-(p-tol-yl)phospho-ric triamide.

Pourayoubi Mehrdad M   Elahi Behrouz B   Parvez Masood M  

Acta crystallographica. Section E, Structure reports online 20111109 Pt 12

The asymmetric unit of the title compound, C(23)H(28)N(3)OP, contains two independent mol-ecules with significant conformational differences. For example, the torsion angles N-C-C-C involving the N-benzyl moieties are 57.3 (7) and 11.6 (8)° in one mol-ecule and 76.5 (7) and 97.4 (7)° in the other. In each mol-ecule, the P atom exhibits a distorted tetra-hedral conformation [the bond angles at P are in the ranges 104.7 (2)-115.2 (2) and 105.1 (2)-115.1 (2)° in the two molecules], and the phosphor  ...[more]

Similar Datasets

Unknown N,N'-Dibenzyl-N,N'-dimethyl-N''-(methyl-sulfon-yl)phospho-ric triamide.
| S-EPMC3120462 | biostudies-literature
Unknown N,N'-Dibenzyl-N,N'-dimethyl-N''-(4-nitro-benzo-yl)phospho-ric triamide.
| S-EPMC3089276 | biostudies-literature
Unknown N,N'-Dibenzyl-N''-(2,6-difluoro-benzo-yl)-N,N'-dimethyl-phospho-ric triamide.
| S-EPMC2983404 | biostudies-literature
Unknown N,N'-Dibenzyl-N,N'-dimethyl-N''-(2-phenyl-acet-yl)phospho-ric triamide.
| S-EPMC3239060 | biostudies-literature
Unknown N,N'-Dibenzyl-N''-(2-chloro-acet-yl)-N,N'-dimethyl-phospho-ric triamide.
| S-EPMC3200640 | biostudies-literature
Unknown N,N'-Dibenzyl-N''-(2,4-difluoro-benzo-yl)-N,N'-dimethyl-phospho-ric triamide.
| S-EPMC3274968 | biostudies-literature
Unknown N,N'-Dibenzyl-N''-(2-chloro-2,2-difluoro-acet-yl)-N,N'-dimethyl-phospho-ric triamide.
| S-EPMC3052170 | biostudies-literature
Unknown N,N'-Dibenzyl-N''-(4-bromo-benzo-yl)-N,N'-dimethyl-phospho-ric triamide.
| S-EPMC2960869 | biostudies-other
Unknown N,N'-Dibenzyl-N''-(2-chloro-2,2-difluoro-acet-yl)phospho-ric triamide.
| S-EPMC3470367 | biostudies-literature
Unknown N,N'-Dicyclo-pentyl-N'',N''-dimethyl-phospho-ric triamide.
| S-EPMC3239040 | biostudies-literature