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1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate.

ABSTRACT: In the title compound, C(19)H(19)N(4)O(2) (+)·Cl(-)·C(2)H(3)N, the dihedral angle between the two phenyl rings is 69.57?(8)° while the dihedral angles between the imidazole ring and the phenyl rings are 70.61?(7) and 82.11?(7)°. In the crystal, N-H?Cl, C-H?O, C-H?Cl and C-H?N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent mol-ecules into a two-dimensional hydrogen-bonded network parallel to (001); an intra-molecular C-H?O hydrogen bond is also observed.

SUBMITTER: Liao CY

PROVIDER: S-EPMC3239007 | biostudies-other | 2011 Dec

REPOSITORIES: biostudies-other

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1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate.

Liao Chuang-Yi CY Lee Hon Man HM

Acta crystallographica. Section E, Structure reports online 20111119 Pt 12

In the title compound, C(19)H(19)N(4)O(2) (+)·Cl(-)·C(2)H(3)N, the dihedral angle between the two phenyl rings is 69.57 (8)° while the dihedral angles between the imidazole ring and the phenyl rings are 70.61 (7) and 82.11 (7)°. In the crystal, N-H⋯Cl, C-H⋯O, C-H⋯Cl and C-H⋯N hydrogen bonds link the imidazolium cations, chloride anions and acetonitrile solvent mol-ecules into a two-dimensional hydrogen-bonded network parallel to (001); an intra-molecular C-H⋯O hydrogen bond is also observed. ...[more]

PMID: 22199856

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