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N-Benzyl-4-methyl-6-phenyl-pyrimidin-2-amine.

ABSTRACT: In the title compound, C(18)H(17)N(3), the dihedral angles between the central pyrimidine ring and its directly-bonded and N-bonded pendant phenyl rings are 25.48?(6) and 80.33?(6)°, respectively. The dihedral angle between the phenyl rings is 79.66?(6)°. In the crystal, inversion dimers linked by pairs of N-H?N hydrogen bonds generate R(2) (2)(8) loops. The crystal structure also features weak ?-? [centroid-centroid separation = 3.6720?(7)?Å] and C-H?? inter-actions.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3247345 | biostudies-other | 2011 Nov

REPOSITORIES: biostudies-other

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N-Benzyl-4-methyl-6-phenyl-pyrimidin-2-amine.

Fun Hoong-Kun HK Hemamalini Madhukar M Hazra Anita A Goswami Shyamaprosad S

Acta crystallographica. Section E, Structure reports online 20111012 Pt 11

In the title compound, C(18)H(17)N(3), the dihedral angles between the central pyrimidine ring and its directly-bonded and N-bonded pendant phenyl rings are 25.48 (6) and 80.33 (6)°, respectively. The dihedral angle between the phenyl rings is 79.66 (6)°. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds generate R(2) (2)(8) loops. The crystal structure also features weak π-π [centroid-centroid separation = 3.6720 (7) Å] and C-H⋯π inter-actions. ...[more]

PMID: 22219963

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