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Trans-Bis(thio-cyanato-?N)tetra-kis-(3,4,5-trimethyl-1H-pyrazole-?N)nickel(II)-3,4,5-trimethyl-1H-pyrazole (1/1).

ABSTRACT: In the title compound, [Ni(NCS)(2)(C(6)H(10)N(2))(4)]·C(6)H(10)N(2), the asymmetric unit comprises a Ni(II) complex and a co-crystallised mol-ecule of 3,4,5-trimethyl-1H-pyrazole (PzMe(3)). The Ni(II) atom is coordinated by four PzMe(3) mol-ecules and two thio-cyanate anions to define a trans N(4)S(2) distorted octa-hedral geometry. A number of intra-molecular N-H?N, N-H?S and C-H?N inter-actions contribute to the stability of the complex. The crystal structure is stabilized by inter-molecular N-H?S inter-actions, which link neighbouring mol-ecules into chains along the a axis.

SUBMITTER: Hossaini Sadr M 

PROVIDER: S-EPMC3247526 | biostudies-other | 2011 Nov

REPOSITORIES: biostudies-other

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trans-Bis(thio-cyanato-κN)tetra-kis-(3,4,5-trimethyl-1H-pyrazole-κN)nickel(II)-3,4,5-trimethyl-1H-pyrazole (1/1).

Hossaini Sadr Moayad M   Engle James T JT   Ziegler Christopher J CJ   Soltani Behzad B   Mousavi Zahra Z  

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

In the title compound, [Ni(NCS)(2)(C(6)H(10)N(2))(4)]·C(6)H(10)N(2), the asymmetric unit comprises a Ni(II) complex and a co-crystallised mol-ecule of 3,4,5-trimethyl-1H-pyrazole (PzMe(3)). The Ni(II) atom is coordinated by four PzMe(3) mol-ecules and two thio-cyanate anions to define a trans N(4)S(2) distorted octa-hedral geometry. A number of intra-molecular N-H⋯N, N-H⋯S and C-H⋯N inter-actions contribute to the stability of the complex. The crystal structure is stabilized by inter-molecular N  ...[more]

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