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Dichlorido{2-[(3,4-dimethyl-phen-yl)imino-meth-yl]pyridine-?N,N'}copper(II).

ABSTRACT: In the title complex, [CuCl(2)(C(14)H(14)N(2))], the Cu(II) atom exhibits a very distorted tetra-hedral coordination geometry involving two chloride ions and two N-atom donors from the Schiff base ligand. The range for the six bond angles about the Cu(2+) cation is 81.49?(11)-145.95?(9)°. The chelate ring including the Cu(II) atom is approximately planar, with a maximum deviation of 0.039?(4)?Å for one of the C atoms; this plane forms a dihedral angle of 46.69?(9)° with the CuCl(2) plane.

SUBMITTER: Khalaj M

PROVIDER: S-EPMC3247544 | biostudies-other | 2011 Nov

REPOSITORIES: biostudies-other

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Dichlorido{2-[(3,4-dimethyl-phen-yl)imino-meth-yl]pyridine-κN,N'}copper(II).

Khalaj Mehdi M Dehghanpour Saeed S Salehzadeh Sadegh S Mahmoudi Ali A

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

In the title complex, [CuCl(2)(C(14)H(14)N(2))], the Cu(II) atom exhibits a very distorted tetra-hedral coordination geometry involving two chloride ions and two N-atom donors from the Schiff base ligand. The range for the six bond angles about the Cu(2+) cation is 81.49 (11)-145.95 (9)°. The chelate ring including the Cu(II) atom is approximately planar, with a maximum deviation of 0.039 (4) Å for one of the C atoms; this plane forms a dihedral angle of 46.69 (9)° with the CuCl(2) plane. ...[more]

PMID: 22219849

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